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Synthesis, Crystal Structure, and Spectra Properties of the Cadmium (II) Complex with Bis(N-allylbenzimidazol-2-ylmethyl)benzylamine

A novel complex of cadmium (II) picrate (pic) with V-shaped ligand bis(N-allylbenzimidazol-2-ylmethyl)benzylamine (babb), with composition [Cd(babb)(2)](pic)(2), was synthesized and characterized by elemental analyses and electrical conductivity, IR, and UV/visible spectra. The crystal structure of...

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Autores principales: Wu, Huilu, Yuan, Jingkun, Bai, Ying, Kou, Fan, Jia, Fei, Liu, Bin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Hindawi Publishing Corporation 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3189465/
https://www.ncbi.nlm.nih.gov/pubmed/22007154
http://dx.doi.org/10.1155/2011/705989
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author Wu, Huilu
Yuan, Jingkun
Bai, Ying
Kou, Fan
Jia, Fei
Liu, Bin
author_facet Wu, Huilu
Yuan, Jingkun
Bai, Ying
Kou, Fan
Jia, Fei
Liu, Bin
author_sort Wu, Huilu
collection PubMed
description A novel complex of cadmium (II) picrate (pic) with V-shaped ligand bis(N-allylbenzimidazol-2-ylmethyl)benzylamine (babb), with composition [Cd(babb)(2)](pic)(2), was synthesized and characterized by elemental analyses and electrical conductivity, IR, and UV/visible spectra. The crystal structure of the complex has been determined by the single-crystal X-ray diffraction. In the complex, the coordination sphere around Cd (II) is distorted octahedral, six nitrogen atoms involved in coordination afforded by two tridentate ligand babb. Moreover, The DNA-binding properties of the ligand babb and Cd (II) complex were investigated by spectrophotometric methods and viscosity measurements, and the results suggest that they bind to DNA via an intercalation binding mode, and the Cd (II) complex shows higher affinity than the ligand.
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spelling pubmed-31894652011-10-17 Synthesis, Crystal Structure, and Spectra Properties of the Cadmium (II) Complex with Bis(N-allylbenzimidazol-2-ylmethyl)benzylamine Wu, Huilu Yuan, Jingkun Bai, Ying Kou, Fan Jia, Fei Liu, Bin Bioinorg Chem Appl Research Article A novel complex of cadmium (II) picrate (pic) with V-shaped ligand bis(N-allylbenzimidazol-2-ylmethyl)benzylamine (babb), with composition [Cd(babb)(2)](pic)(2), was synthesized and characterized by elemental analyses and electrical conductivity, IR, and UV/visible spectra. The crystal structure of the complex has been determined by the single-crystal X-ray diffraction. In the complex, the coordination sphere around Cd (II) is distorted octahedral, six nitrogen atoms involved in coordination afforded by two tridentate ligand babb. Moreover, The DNA-binding properties of the ligand babb and Cd (II) complex were investigated by spectrophotometric methods and viscosity measurements, and the results suggest that they bind to DNA via an intercalation binding mode, and the Cd (II) complex shows higher affinity than the ligand. Hindawi Publishing Corporation 2011 2011-10-05 /pmc/articles/PMC3189465/ /pubmed/22007154 http://dx.doi.org/10.1155/2011/705989 Text en Copyright © 2011 Huilu Wu et al. https://creativecommons.org/licenses/by/3.0/ This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Research Article
Wu, Huilu
Yuan, Jingkun
Bai, Ying
Kou, Fan
Jia, Fei
Liu, Bin
Synthesis, Crystal Structure, and Spectra Properties of the Cadmium (II) Complex with Bis(N-allylbenzimidazol-2-ylmethyl)benzylamine
title Synthesis, Crystal Structure, and Spectra Properties of the Cadmium (II) Complex with Bis(N-allylbenzimidazol-2-ylmethyl)benzylamine
title_full Synthesis, Crystal Structure, and Spectra Properties of the Cadmium (II) Complex with Bis(N-allylbenzimidazol-2-ylmethyl)benzylamine
title_fullStr Synthesis, Crystal Structure, and Spectra Properties of the Cadmium (II) Complex with Bis(N-allylbenzimidazol-2-ylmethyl)benzylamine
title_full_unstemmed Synthesis, Crystal Structure, and Spectra Properties of the Cadmium (II) Complex with Bis(N-allylbenzimidazol-2-ylmethyl)benzylamine
title_short Synthesis, Crystal Structure, and Spectra Properties of the Cadmium (II) Complex with Bis(N-allylbenzimidazol-2-ylmethyl)benzylamine
title_sort synthesis, crystal structure, and spectra properties of the cadmium (ii) complex with bis(n-allylbenzimidazol-2-ylmethyl)benzylamine
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3189465/
https://www.ncbi.nlm.nih.gov/pubmed/22007154
http://dx.doi.org/10.1155/2011/705989
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