Cargando…

Bis{2-[(2-hy­droxy-2-methyl­prop­yl)imino­meth­yl]-4-nitro­phenolato}nickel(II) dimethyl­formamide monosolvate

In the title compound, [Ni(C(11)H(13)N(2)O(4))(2)]·C(3)H(7)NO, the Ni(II) ion is octa­hedrally coordinated in an N(2)O(4) environment by two identical Schiff base ligands. The Ni—O bond lengths range from 2.004 (2) to 2.106 (2) Å, while the Ni—N bond lengths are 2.038 (2) and 2.0465 (19) Å. The cis...

Descripción completa

Detalles Bibliográficos
Autores principales: Ayikoé, Kouassi, Gultneh, Yilma, Butcher, Ray J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200578/
https://www.ncbi.nlm.nih.gov/pubmed/22058849
http://dx.doi.org/10.1107/S1600536811031229
Descripción
Sumario:In the title compound, [Ni(C(11)H(13)N(2)O(4))(2)]·C(3)H(7)NO, the Ni(II) ion is octa­hedrally coordinated in an N(2)O(4) environment by two identical Schiff base ligands. The Ni—O bond lengths range from 2.004 (2) to 2.106 (2) Å, while the Ni—N bond lengths are 2.038 (2) and 2.0465 (19) Å. The cis bond angles range from 78.64 (8) to 97.30 (8)°, with the former being due to the small bite of the amino­alcohol ligand, while the trans bond angles range from 167.86 (8) to 171.23 (8)°. One of the alcohol H atoms forms a hydrogen bond with the dimethyl­formamide (DMF) solvent mol­ecule, while the other links mol­ecules into chains along the b axis through inter­molecular O—H⋯O hydrogen bonds. There are bifurcated C—H⋯O inter­actions involving one of the nitro groups between parallel stacks of mol­ecules in the b-axis direction.