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Bis{2-[(2-hydroxy-2-methylpropyl)iminomethyl]-4-nitrophenolato}nickel(II) dimethylformamide monosolvate
In the title compound, [Ni(C(11)H(13)N(2)O(4))(2)]·C(3)H(7)NO, the Ni(II) ion is octahedrally coordinated in an N(2)O(4) environment by two identical Schiff base ligands. The Ni—O bond lengths range from 2.004 (2) to 2.106 (2) Å, while the Ni—N bond lengths are 2.038 (2) and 2.0465 (19) Å. The cis...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200578/ https://www.ncbi.nlm.nih.gov/pubmed/22058849 http://dx.doi.org/10.1107/S1600536811031229 |
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author | Ayikoé, Kouassi Gultneh, Yilma Butcher, Ray J. |
author_facet | Ayikoé, Kouassi Gultneh, Yilma Butcher, Ray J. |
author_sort | Ayikoé, Kouassi |
collection | PubMed |
description | In the title compound, [Ni(C(11)H(13)N(2)O(4))(2)]·C(3)H(7)NO, the Ni(II) ion is octahedrally coordinated in an N(2)O(4) environment by two identical Schiff base ligands. The Ni—O bond lengths range from 2.004 (2) to 2.106 (2) Å, while the Ni—N bond lengths are 2.038 (2) and 2.0465 (19) Å. The cis bond angles range from 78.64 (8) to 97.30 (8)°, with the former being due to the small bite of the aminoalcohol ligand, while the trans bond angles range from 167.86 (8) to 171.23 (8)°. One of the alcohol H atoms forms a hydrogen bond with the dimethylformamide (DMF) solvent molecule, while the other links molecules into chains along the b axis through intermolecular O—H⋯O hydrogen bonds. There are bifurcated C—H⋯O interactions involving one of the nitro groups between parallel stacks of molecules in the b-axis direction. |
format | Online Article Text |
id | pubmed-3200578 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32005782011-11-06 Bis{2-[(2-hydroxy-2-methylpropyl)iminomethyl]-4-nitrophenolato}nickel(II) dimethylformamide monosolvate Ayikoé, Kouassi Gultneh, Yilma Butcher, Ray J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(11)H(13)N(2)O(4))(2)]·C(3)H(7)NO, the Ni(II) ion is octahedrally coordinated in an N(2)O(4) environment by two identical Schiff base ligands. The Ni—O bond lengths range from 2.004 (2) to 2.106 (2) Å, while the Ni—N bond lengths are 2.038 (2) and 2.0465 (19) Å. The cis bond angles range from 78.64 (8) to 97.30 (8)°, with the former being due to the small bite of the aminoalcohol ligand, while the trans bond angles range from 167.86 (8) to 171.23 (8)°. One of the alcohol H atoms forms a hydrogen bond with the dimethylformamide (DMF) solvent molecule, while the other links molecules into chains along the b axis through intermolecular O—H⋯O hydrogen bonds. There are bifurcated C—H⋯O interactions involving one of the nitro groups between parallel stacks of molecules in the b-axis direction. International Union of Crystallography 2011-08-06 /pmc/articles/PMC3200578/ /pubmed/22058849 http://dx.doi.org/10.1107/S1600536811031229 Text en © Ayikoé et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ayikoé, Kouassi Gultneh, Yilma Butcher, Ray J. Bis{2-[(2-hydroxy-2-methylpropyl)iminomethyl]-4-nitrophenolato}nickel(II) dimethylformamide monosolvate |
title | Bis{2-[(2-hydroxy-2-methylpropyl)iminomethyl]-4-nitrophenolato}nickel(II) dimethylformamide monosolvate |
title_full | Bis{2-[(2-hydroxy-2-methylpropyl)iminomethyl]-4-nitrophenolato}nickel(II) dimethylformamide monosolvate |
title_fullStr | Bis{2-[(2-hydroxy-2-methylpropyl)iminomethyl]-4-nitrophenolato}nickel(II) dimethylformamide monosolvate |
title_full_unstemmed | Bis{2-[(2-hydroxy-2-methylpropyl)iminomethyl]-4-nitrophenolato}nickel(II) dimethylformamide monosolvate |
title_short | Bis{2-[(2-hydroxy-2-methylpropyl)iminomethyl]-4-nitrophenolato}nickel(II) dimethylformamide monosolvate |
title_sort | bis{2-[(2-hydroxy-2-methylpropyl)iminomethyl]-4-nitrophenolato}nickel(ii) dimethylformamide monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200578/ https://www.ncbi.nlm.nih.gov/pubmed/22058849 http://dx.doi.org/10.1107/S1600536811031229 |
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