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Bis{2-[(2-hy­droxy-2-methyl­prop­yl)imino­meth­yl]-4-nitro­phenolato}nickel(II) dimethyl­formamide monosolvate

In the title compound, [Ni(C(11)H(13)N(2)O(4))(2)]·C(3)H(7)NO, the Ni(II) ion is octa­hedrally coordinated in an N(2)O(4) environment by two identical Schiff base ligands. The Ni—O bond lengths range from 2.004 (2) to 2.106 (2) Å, while the Ni—N bond lengths are 2.038 (2) and 2.0465 (19) Å. The cis...

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Autores principales: Ayikoé, Kouassi, Gultneh, Yilma, Butcher, Ray J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200578/
https://www.ncbi.nlm.nih.gov/pubmed/22058849
http://dx.doi.org/10.1107/S1600536811031229
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author Ayikoé, Kouassi
Gultneh, Yilma
Butcher, Ray J.
author_facet Ayikoé, Kouassi
Gultneh, Yilma
Butcher, Ray J.
author_sort Ayikoé, Kouassi
collection PubMed
description In the title compound, [Ni(C(11)H(13)N(2)O(4))(2)]·C(3)H(7)NO, the Ni(II) ion is octa­hedrally coordinated in an N(2)O(4) environment by two identical Schiff base ligands. The Ni—O bond lengths range from 2.004 (2) to 2.106 (2) Å, while the Ni—N bond lengths are 2.038 (2) and 2.0465 (19) Å. The cis bond angles range from 78.64 (8) to 97.30 (8)°, with the former being due to the small bite of the amino­alcohol ligand, while the trans bond angles range from 167.86 (8) to 171.23 (8)°. One of the alcohol H atoms forms a hydrogen bond with the dimethyl­formamide (DMF) solvent mol­ecule, while the other links mol­ecules into chains along the b axis through inter­molecular O—H⋯O hydrogen bonds. There are bifurcated C—H⋯O inter­actions involving one of the nitro groups between parallel stacks of mol­ecules in the b-axis direction.
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spelling pubmed-32005782011-11-06 Bis{2-[(2-hy­droxy-2-methyl­prop­yl)imino­meth­yl]-4-nitro­phenolato}nickel(II) dimethyl­formamide monosolvate Ayikoé, Kouassi Gultneh, Yilma Butcher, Ray J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(11)H(13)N(2)O(4))(2)]·C(3)H(7)NO, the Ni(II) ion is octa­hedrally coordinated in an N(2)O(4) environment by two identical Schiff base ligands. The Ni—O bond lengths range from 2.004 (2) to 2.106 (2) Å, while the Ni—N bond lengths are 2.038 (2) and 2.0465 (19) Å. The cis bond angles range from 78.64 (8) to 97.30 (8)°, with the former being due to the small bite of the amino­alcohol ligand, while the trans bond angles range from 167.86 (8) to 171.23 (8)°. One of the alcohol H atoms forms a hydrogen bond with the dimethyl­formamide (DMF) solvent mol­ecule, while the other links mol­ecules into chains along the b axis through inter­molecular O—H⋯O hydrogen bonds. There are bifurcated C—H⋯O inter­actions involving one of the nitro groups between parallel stacks of mol­ecules in the b-axis direction. International Union of Crystallography 2011-08-06 /pmc/articles/PMC3200578/ /pubmed/22058849 http://dx.doi.org/10.1107/S1600536811031229 Text en © Ayikoé et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ayikoé, Kouassi
Gultneh, Yilma
Butcher, Ray J.
Bis{2-[(2-hy­droxy-2-methyl­prop­yl)imino­meth­yl]-4-nitro­phenolato}nickel(II) dimethyl­formamide monosolvate
title Bis{2-[(2-hy­droxy-2-methyl­prop­yl)imino­meth­yl]-4-nitro­phenolato}nickel(II) dimethyl­formamide monosolvate
title_full Bis{2-[(2-hy­droxy-2-methyl­prop­yl)imino­meth­yl]-4-nitro­phenolato}nickel(II) dimethyl­formamide monosolvate
title_fullStr Bis{2-[(2-hy­droxy-2-methyl­prop­yl)imino­meth­yl]-4-nitro­phenolato}nickel(II) dimethyl­formamide monosolvate
title_full_unstemmed Bis{2-[(2-hy­droxy-2-methyl­prop­yl)imino­meth­yl]-4-nitro­phenolato}nickel(II) dimethyl­formamide monosolvate
title_short Bis{2-[(2-hy­droxy-2-methyl­prop­yl)imino­meth­yl]-4-nitro­phenolato}nickel(II) dimethyl­formamide monosolvate
title_sort bis{2-[(2-hy­droxy-2-methyl­prop­yl)imino­meth­yl]-4-nitro­phenolato}nickel(ii) dimethyl­formamide monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200578/
https://www.ncbi.nlm.nih.gov/pubmed/22058849
http://dx.doi.org/10.1107/S1600536811031229
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AT butcherrayj bis22hydroxy2methylpropyliminomethyl4nitrophenolatonickeliidimethylformamidemonosolvate