Bis(N,N′-dimethyl­ethylenediammonium) tris­(oxalato-κ(2) O (1),O (2))cobaltate(II) dihydrate: an ion-pair complex

The Co(II) ion in the title complex, (C(4)H(14)N(2))(2)[Co(C(2)O(4))(3)]·2H(2)O, is coordinated by three oxalate ions, resulting in a distorted octa­hedral geometry. Two uncoordinated water mol­ecules are present in asymmetric unit. Inter­molecular N—H⋯O and O—H⋯O hydrogen bonds between the differen...

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Detalles Bibliográficos
Autores principales: Gaye, Papa Aly, Sy, Adama, Thiam, Ibrahima Elhadj, Gaye, Mohamed, Retailleau, Pascal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200586/
https://www.ncbi.nlm.nih.gov/pubmed/22058871
http://dx.doi.org/10.1107/S1600536811031357
Descripción
Sumario:The Co(II) ion in the title complex, (C(4)H(14)N(2))(2)[Co(C(2)O(4))(3)]·2H(2)O, is coordinated by three oxalate ions, resulting in a distorted octa­hedral geometry. Two uncoordinated water mol­ecules are present in asymmetric unit. Inter­molecular N—H⋯O and O—H⋯O hydrogen bonds between the different entities stabilize the crystal structure.

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