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Bis(N,N′-dimethylethylenediammonium) tris(oxalato-κ(2) O (1),O (2))cobaltate(II) dihydrate: an ion-pair complex
The Co(II) ion in the title complex, (C(4)H(14)N(2))(2)[Co(C(2)O(4))(3)]·2H(2)O, is coordinated by three oxalate ions, resulting in a distorted octahedral geometry. Two uncoordinated water molecules are present in asymmetric unit. Intermolecular N—H⋯O and O—H⋯O hydrogen bonds between the differen...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200586/ https://www.ncbi.nlm.nih.gov/pubmed/22058871 http://dx.doi.org/10.1107/S1600536811031357 |
| _version_ | 1782214704050995200 |
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| author | Gaye, Papa Aly Sy, Adama Thiam, Ibrahima Elhadj Gaye, Mohamed Retailleau, Pascal |
| author_facet | Gaye, Papa Aly Sy, Adama Thiam, Ibrahima Elhadj Gaye, Mohamed Retailleau, Pascal |
| author_sort | Gaye, Papa Aly |
| collection | PubMed |
| description | The Co(II) ion in the title complex, (C(4)H(14)N(2))(2)[Co(C(2)O(4))(3)]·2H(2)O, is coordinated by three oxalate ions, resulting in a distorted octahedral geometry. Two uncoordinated water molecules are present in asymmetric unit. Intermolecular N—H⋯O and O—H⋯O hydrogen bonds between the different entities stabilize the crystal structure. |
| format | Online Article Text |
| id | pubmed-3200586 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32005862011-11-06 Bis(N,N′-dimethylethylenediammonium) tris(oxalato-κ(2) O (1),O (2))cobaltate(II) dihydrate: an ion-pair complex Gaye, Papa Aly Sy, Adama Thiam, Ibrahima Elhadj Gaye, Mohamed Retailleau, Pascal Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Co(II) ion in the title complex, (C(4)H(14)N(2))(2)[Co(C(2)O(4))(3)]·2H(2)O, is coordinated by three oxalate ions, resulting in a distorted octahedral geometry. Two uncoordinated water molecules are present in asymmetric unit. Intermolecular N—H⋯O and O—H⋯O hydrogen bonds between the different entities stabilize the crystal structure. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200586/ /pubmed/22058871 http://dx.doi.org/10.1107/S1600536811031357 Text en © Gaye et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Gaye, Papa Aly Sy, Adama Thiam, Ibrahima Elhadj Gaye, Mohamed Retailleau, Pascal Bis(N,N′-dimethylethylenediammonium) tris(oxalato-κ(2) O (1),O (2))cobaltate(II) dihydrate: an ion-pair complex |
| title | Bis(N,N′-dimethylethylenediammonium) tris(oxalato-κ(2)
O
(1),O
(2))cobaltate(II) dihydrate: an ion-pair complex |
| title_full | Bis(N,N′-dimethylethylenediammonium) tris(oxalato-κ(2)
O
(1),O
(2))cobaltate(II) dihydrate: an ion-pair complex |
| title_fullStr | Bis(N,N′-dimethylethylenediammonium) tris(oxalato-κ(2)
O
(1),O
(2))cobaltate(II) dihydrate: an ion-pair complex |
| title_full_unstemmed | Bis(N,N′-dimethylethylenediammonium) tris(oxalato-κ(2)
O
(1),O
(2))cobaltate(II) dihydrate: an ion-pair complex |
| title_short | Bis(N,N′-dimethylethylenediammonium) tris(oxalato-κ(2)
O
(1),O
(2))cobaltate(II) dihydrate: an ion-pair complex |
| title_sort | bis(n,n′-dimethylethylenediammonium) tris(oxalato-κ(2)
o
(1),o
(2))cobaltate(ii) dihydrate: an ion-pair complex |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200586/ https://www.ncbi.nlm.nih.gov/pubmed/22058871 http://dx.doi.org/10.1107/S1600536811031357 |
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