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2-Amino-6-methyl­pyridinium 2-carb­oxy­benzoate

In the title mol­ecular salt, C(6)H(9)N(2) (+)·C(8)H(5)O(4) (−), an intra­molecular O—H⋯O hydrogen bond occurs within the anion, thereby generating an S(7) ring, which may correlate with the fact that both the carb­oxy­lic acid and carboxyl­ate groups are almost coplanar with their attached rings [d...

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Detalles Bibliográficos
Autores principales: Hemamalini, Madhukar, Razak, Ibrahim Abdul, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200597/
https://www.ncbi.nlm.nih.gov/pubmed/22058994
http://dx.doi.org/10.1107/S1600536811033174
Descripción
Sumario:In the title mol­ecular salt, C(6)H(9)N(2) (+)·C(8)H(5)O(4) (−), an intra­molecular O—H⋯O hydrogen bond occurs within the anion, thereby generating an S(7) ring, which may correlate with the fact that both the carb­oxy­lic acid and carboxyl­ate groups are almost coplanar with their attached rings [dihedral angles = 2.9 (3) and 5.2 (3)°, respectively]. In the crystal, each cation is linked to its adjacent anion by two N—H⋯O hydrogen bonds; the dihedral angle between the pyridine and benzene rings is 2.22 (10)°. The ion pairs are linked by further N—H⋯O inter­actions.