(1E,4E)-1,5-Bis(thio­phen-3-yl)penta-1,4-dien-3-one

The title compound, C(13)H(10)OS(2), exhibits twists between the central C(3)O and ethene residues [O—C—C—C torsion angles = −8.4 (3) and 11.8 (3)°], and between the ethene and adjacent thio­phenyl residues [C—C—C—C torsion angles = −4.2 (3) and 10.5 (3)°]. As a result, the mol­ecule is non-planar,...

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Detalles Bibliográficos
Autores principales: Shalini, S., Girija, C. R., Jotani, Mukesh M., Rajashekhar, B., Rao, Nageswar, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200598/
https://www.ncbi.nlm.nih.gov/pubmed/22058969
http://dx.doi.org/10.1107/S160053681103248X
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author Shalini, S.
Girija, C. R.
Jotani, Mukesh M.
Rajashekhar, B.
Rao, Nageswar
Tiekink, Edward R. T.
author_facet Shalini, S.
Girija, C. R.
Jotani, Mukesh M.
Rajashekhar, B.
Rao, Nageswar
Tiekink, Edward R. T.
author_sort Shalini, S.
collection PubMed
description The title compound, C(13)H(10)OS(2), exhibits twists between the central C(3)O and ethene residues [O—C—C—C torsion angles = −8.4 (3) and 11.8 (3)°], and between the ethene and adjacent thio­phenyl residues [C—C—C—C torsion angles = −4.2 (3) and 10.5 (3)°]. As a result, the mol­ecule is non-planar, the dihedral angle formed between the terminal thio­phenyl groups being 15.45 (10)°. The presence of C—H⋯O inter­actions involving the bifurcated carbonyl O atom leads to supra­molecular arrays in the ac plane. These are linked into a three-dimensional architecture by C—H⋯π inter­actions involving both thio­phenyl residues.
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spelling pubmed-32005982011-11-06 (1E,4E)-1,5-Bis(thio­phen-3-yl)penta-1,4-dien-3-one Shalini, S. Girija, C. R. Jotani, Mukesh M. Rajashekhar, B. Rao, Nageswar Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(10)OS(2), exhibits twists between the central C(3)O and ethene residues [O—C—C—C torsion angles = −8.4 (3) and 11.8 (3)°], and between the ethene and adjacent thio­phenyl residues [C—C—C—C torsion angles = −4.2 (3) and 10.5 (3)°]. As a result, the mol­ecule is non-planar, the dihedral angle formed between the terminal thio­phenyl groups being 15.45 (10)°. The presence of C—H⋯O inter­actions involving the bifurcated carbonyl O atom leads to supra­molecular arrays in the ac plane. These are linked into a three-dimensional architecture by C—H⋯π inter­actions involving both thio­phenyl residues. International Union of Crystallography 2011-08-17 /pmc/articles/PMC3200598/ /pubmed/22058969 http://dx.doi.org/10.1107/S160053681103248X Text en © Shalini et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shalini, S.
Girija, C. R.
Jotani, Mukesh M.
Rajashekhar, B.
Rao, Nageswar
Tiekink, Edward R. T.
(1E,4E)-1,5-Bis(thio­phen-3-yl)penta-1,4-dien-3-one
title (1E,4E)-1,5-Bis(thio­phen-3-yl)penta-1,4-dien-3-one
title_full (1E,4E)-1,5-Bis(thio­phen-3-yl)penta-1,4-dien-3-one
title_fullStr (1E,4E)-1,5-Bis(thio­phen-3-yl)penta-1,4-dien-3-one
title_full_unstemmed (1E,4E)-1,5-Bis(thio­phen-3-yl)penta-1,4-dien-3-one
title_short (1E,4E)-1,5-Bis(thio­phen-3-yl)penta-1,4-dien-3-one
title_sort (1e,4e)-1,5-bis(thio­phen-3-yl)penta-1,4-dien-3-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200598/
https://www.ncbi.nlm.nih.gov/pubmed/22058969
http://dx.doi.org/10.1107/S160053681103248X
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