5-(4-Bromo-2-nitro­phen­yl)-1,3,4-thia­diazol-2-amine

The title compound, C(8)H(5)BrN(4)O(2)S, was synthesized by the reaction of 4-bromo-2-nitro­benzoic acid with thio­semi­carbazide. The dihedral angle between the thia­diazole and benzene rings is 40.5 (2)°. In the crystal, the strongest N—H⋯N inter­molecular hydrogen bond, between the amine group an...

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Detalles Bibliográficos
Autores principales: Zhang, Jian-qiang, He, Qiu, Jiang, Qianghua, Mu, Haipin, Wan, Rong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200604/
https://www.ncbi.nlm.nih.gov/pubmed/22058914
http://dx.doi.org/10.1107/S1600536811030868
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author Zhang, Jian-qiang
He, Qiu
Jiang, Qianghua
Mu, Haipin
Wan, Rong
author_facet Zhang, Jian-qiang
He, Qiu
Jiang, Qianghua
Mu, Haipin
Wan, Rong
author_sort Zhang, Jian-qiang
collection PubMed
description The title compound, C(8)H(5)BrN(4)O(2)S, was synthesized by the reaction of 4-bromo-2-nitro­benzoic acid with thio­semi­carbazide. The dihedral angle between the thia­diazole and benzene rings is 40.5 (2)°. In the crystal, the strongest N—H⋯N inter­molecular hydrogen bond, between the amine group and one thia­diazole N atom, forms centrosymmetric dimers. The other amine H atom extends the supra­molecular network, forming an N—H⋯N contact with the other thia­diazole N atom.
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spelling pubmed-32006042011-11-06 5-(4-Bromo-2-nitro­phen­yl)-1,3,4-thia­diazol-2-amine Zhang, Jian-qiang He, Qiu Jiang, Qianghua Mu, Haipin Wan, Rong Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(8)H(5)BrN(4)O(2)S, was synthesized by the reaction of 4-bromo-2-nitro­benzoic acid with thio­semi­carbazide. The dihedral angle between the thia­diazole and benzene rings is 40.5 (2)°. In the crystal, the strongest N—H⋯N inter­molecular hydrogen bond, between the amine group and one thia­diazole N atom, forms centrosymmetric dimers. The other amine H atom extends the supra­molecular network, forming an N—H⋯N contact with the other thia­diazole N atom. International Union of Crystallography 2011-08-06 /pmc/articles/PMC3200604/ /pubmed/22058914 http://dx.doi.org/10.1107/S1600536811030868 Text en © Zhang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhang, Jian-qiang
He, Qiu
Jiang, Qianghua
Mu, Haipin
Wan, Rong
5-(4-Bromo-2-nitro­phen­yl)-1,3,4-thia­diazol-2-amine
title 5-(4-Bromo-2-nitro­phen­yl)-1,3,4-thia­diazol-2-amine
title_full 5-(4-Bromo-2-nitro­phen­yl)-1,3,4-thia­diazol-2-amine
title_fullStr 5-(4-Bromo-2-nitro­phen­yl)-1,3,4-thia­diazol-2-amine
title_full_unstemmed 5-(4-Bromo-2-nitro­phen­yl)-1,3,4-thia­diazol-2-amine
title_short 5-(4-Bromo-2-nitro­phen­yl)-1,3,4-thia­diazol-2-amine
title_sort 5-(4-bromo-2-nitro­phen­yl)-1,3,4-thia­diazol-2-amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200604/
https://www.ncbi.nlm.nih.gov/pubmed/22058914
http://dx.doi.org/10.1107/S1600536811030868
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AT muhaipin 54bromo2nitrophenyl134thiadiazol2amine
AT wanrong 54bromo2nitrophenyl134thiadiazol2amine

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