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Di-μ-acetato-κ(3) O,O′:O′;κ(3) O:O,O′-bis[(acetato-κ(2) O,O′)bis(5-nitro-1,10-phenanthroline-κ(2) N,N′)cadmium]
In the binuclear title compound, [Cd(2)(C(2)H(3)O(2))(4)(C(12)H(7)N(3)O(2))(2)], the Cd(II) cations are linked by carboxylate O atoms into a four-membered Cd(2)O(2) rhombic ring with a Cd⋯ Cd separation of 3.7515 (5) Å. Each Cd(II) atom is seven-coordinated by a bidentate 5-nitro-1,10-phenanthrolin...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200609/ https://www.ncbi.nlm.nih.gov/pubmed/22058861 http://dx.doi.org/10.1107/S1600536811032259 |
Sumario: | In the binuclear title compound, [Cd(2)(C(2)H(3)O(2))(4)(C(12)H(7)N(3)O(2))(2)], the Cd(II) cations are linked by carboxylate O atoms into a four-membered Cd(2)O(2) rhombic ring with a Cd⋯ Cd separation of 3.7515 (5) Å. Each Cd(II) atom is seven-coordinated by a bidentate 5-nitro-1,10-phenanthroline (5-NO(2)-phen) ligand and two bidentate acetate anions, one of which also acts as a bridge linking the two Cd atoms. The crystal packing is stabilized by π–π interactions between the phen rings of neighboring molecules, with centroid–centroid distances of 3.491 (2) (intramolecular) and 3.598 (2) Å (intermolecular). |
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