{μ-6,6′-Dimeth­oxy-2,2′-[butane-1,4-diylbis(nitrilo­methanylyl­idene)]diphenolato}trinitratocopper(II)samarium(III)

In the monomeric dinuclear title complex, [CuSm(C(20)H(22)N(2)O(4))(NO(3))(3)], the four-coordinate Cu(II) ion has a square-planar geometry involving two O atoms and two N atoms of the deprotonated Schiff base ligand. The Sm(III) ion is ten-coordinate, chelated by four O donor atoms of the Schiff ba...

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Detalles Bibliográficos
Autores principales: Xing, Jing-Chun, Zhang, Bing, Li, Wen-Zhi, Cui, Xiao-Guang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200624/
https://www.ncbi.nlm.nih.gov/pubmed/22058850
http://dx.doi.org/10.1107/S1600536811031138
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author Xing, Jing-Chun
Zhang, Bing
Li, Wen-Zhi
Cui, Xiao-Guang
author_facet Xing, Jing-Chun
Zhang, Bing
Li, Wen-Zhi
Cui, Xiao-Guang
author_sort Xing, Jing-Chun
collection PubMed
description In the monomeric dinuclear title complex, [CuSm(C(20)H(22)N(2)O(4))(NO(3))(3)], the four-coordinate Cu(II) ion has a square-planar geometry involving two O atoms and two N atoms of the deprotonated Schiff base ligand. The Sm(III) ion is ten-coordinate, chelated by four O donor atoms of the Schiff base and two O atoms each from three bidentate nitrate groups, one of which is disordered over two sites in a 0.55 (7):0.45 (7) ratio.
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spelling pubmed-32006242011-11-06 {μ-6,6′-Dimeth­oxy-2,2′-[butane-1,4-diylbis(nitrilo­methanylyl­idene)]diphenolato}trinitratocopper(II)samarium(III) Xing, Jing-Chun Zhang, Bing Li, Wen-Zhi Cui, Xiao-Guang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the monomeric dinuclear title complex, [CuSm(C(20)H(22)N(2)O(4))(NO(3))(3)], the four-coordinate Cu(II) ion has a square-planar geometry involving two O atoms and two N atoms of the deprotonated Schiff base ligand. The Sm(III) ion is ten-coordinate, chelated by four O donor atoms of the Schiff base and two O atoms each from three bidentate nitrate groups, one of which is disordered over two sites in a 0.55 (7):0.45 (7) ratio. International Union of Crystallography 2011-08-06 /pmc/articles/PMC3200624/ /pubmed/22058850 http://dx.doi.org/10.1107/S1600536811031138 Text en © Xing et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xing, Jing-Chun
Zhang, Bing
Li, Wen-Zhi
Cui, Xiao-Guang
{μ-6,6′-Dimeth­oxy-2,2′-[butane-1,4-diylbis(nitrilo­methanylyl­idene)]diphenolato}trinitratocopper(II)samarium(III)
title {μ-6,6′-Dimeth­oxy-2,2′-[butane-1,4-diylbis(nitrilo­methanylyl­idene)]diphenolato}trinitratocopper(II)samarium(III)
title_full {μ-6,6′-Dimeth­oxy-2,2′-[butane-1,4-diylbis(nitrilo­methanylyl­idene)]diphenolato}trinitratocopper(II)samarium(III)
title_fullStr {μ-6,6′-Dimeth­oxy-2,2′-[butane-1,4-diylbis(nitrilo­methanylyl­idene)]diphenolato}trinitratocopper(II)samarium(III)
title_full_unstemmed {μ-6,6′-Dimeth­oxy-2,2′-[butane-1,4-diylbis(nitrilo­methanylyl­idene)]diphenolato}trinitratocopper(II)samarium(III)
title_short {μ-6,6′-Dimeth­oxy-2,2′-[butane-1,4-diylbis(nitrilo­methanylyl­idene)]diphenolato}trinitratocopper(II)samarium(III)
title_sort {μ-6,6′-dimeth­oxy-2,2′-[butane-1,4-diylbis(nitrilo­methanylyl­idene)]diphenolato}trinitratocopper(ii)samarium(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200624/
https://www.ncbi.nlm.nih.gov/pubmed/22058850
http://dx.doi.org/10.1107/S1600536811031138
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