Cargando…
N,N′-Bis(3-chlorophenyl)malonamide
The asymmetric unit of the title compound, C(15)H(12)Cl(2)N(2)O(2), contains two independent molecules. In both independent molecules, the N—H bond in one of the amide fragments is anti to the meta-chloro group of the adjacent benzene ring and that in the other amide group is syn to the other meta...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200632/ https://www.ncbi.nlm.nih.gov/pubmed/22058926 http://dx.doi.org/10.1107/S1600536811031333 |
Sumario: | The asymmetric unit of the title compound, C(15)H(12)Cl(2)N(2)O(2), contains two independent molecules. In both independent molecules, the N—H bond in one of the amide fragments is anti to the meta-chloro group of the adjacent benzene ring and that in the other amide group is syn to the other meta-chloro group. Furthermore, in both molecules, each amide group is almost coplanar with the adjacent phenyl ring, making dihedral angles of 10.5 (2) and 8.7 (2)° in one molecule and 9.0 (2) and 9.6 (2)° in the other. The planes of the amide groups are inclined at dihedral angles of 83.4 (1) and 87.4 (1)° in the two molecules. In the crystal, molecules are linked into a chain by intermolecular N—H⋯O hydrogen bonds. |
---|