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N,N′-Bis(3-chloro­phen­yl)malonamide

The asymmetric unit of the title compound, C(15)H(12)Cl(2)N(2)O(2), contains two independent mol­ecules. In both independent mol­ecules, the N—H bond in one of the amide fragments is anti to the meta-chloro group of the adjacent benzene ring and that in the other amide group is syn to the other meta...

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Detalles Bibliográficos
Autores principales: Rodrigues, Vinola Z., Foro, Sabine, Gowda, B. Thimme
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200632/
https://www.ncbi.nlm.nih.gov/pubmed/22058926
http://dx.doi.org/10.1107/S1600536811031333
Descripción
Sumario:The asymmetric unit of the title compound, C(15)H(12)Cl(2)N(2)O(2), contains two independent mol­ecules. In both independent mol­ecules, the N—H bond in one of the amide fragments is anti to the meta-chloro group of the adjacent benzene ring and that in the other amide group is syn to the other meta-chloro group. Furthermore, in both mol­ecules, each amide group is almost coplanar with the adjacent phenyl ring, making dihedral angles of 10.5 (2) and 8.7 (2)° in one molecule and 9.0 (2) and 9.6 (2)° in the other. The planes of the amide groups are inclined at dihedral angles of 83.4 (1) and 87.4 (1)° in the two mol­ecules. In the crystal, mol­ecules are linked into a chain by inter­molecular N—H⋯O hydrogen bonds.