N,N′-Bis(3-chloro­phen­yl)malonamide

The asymmetric unit of the title compound, C(15)H(12)Cl(2)N(2)O(2), contains two independent mol­ecules. In both independent mol­ecules, the N—H bond in one of the amide fragments is anti to the meta-chloro group of the adjacent benzene ring and that in the other amide group is syn to the other meta...

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Detalles Bibliográficos
Autores principales: Rodrigues, Vinola Z., Foro, Sabine, Gowda, B. Thimme
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200632/
https://www.ncbi.nlm.nih.gov/pubmed/22058926
http://dx.doi.org/10.1107/S1600536811031333
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author Rodrigues, Vinola Z.
Foro, Sabine
Gowda, B. Thimme
author_facet Rodrigues, Vinola Z.
Foro, Sabine
Gowda, B. Thimme
author_sort Rodrigues, Vinola Z.
collection PubMed
description The asymmetric unit of the title compound, C(15)H(12)Cl(2)N(2)O(2), contains two independent mol­ecules. In both independent mol­ecules, the N—H bond in one of the amide fragments is anti to the meta-chloro group of the adjacent benzene ring and that in the other amide group is syn to the other meta-chloro group. Furthermore, in both mol­ecules, each amide group is almost coplanar with the adjacent phenyl ring, making dihedral angles of 10.5 (2) and 8.7 (2)° in one molecule and 9.0 (2) and 9.6 (2)° in the other. The planes of the amide groups are inclined at dihedral angles of 83.4 (1) and 87.4 (1)° in the two mol­ecules. In the crystal, mol­ecules are linked into a chain by inter­molecular N—H⋯O hydrogen bonds.
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spelling pubmed-32006322011-11-06 N,N′-Bis(3-chloro­phen­yl)malonamide Rodrigues, Vinola Z. Foro, Sabine Gowda, B. Thimme Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(15)H(12)Cl(2)N(2)O(2), contains two independent mol­ecules. In both independent mol­ecules, the N—H bond in one of the amide fragments is anti to the meta-chloro group of the adjacent benzene ring and that in the other amide group is syn to the other meta-chloro group. Furthermore, in both mol­ecules, each amide group is almost coplanar with the adjacent phenyl ring, making dihedral angles of 10.5 (2) and 8.7 (2)° in one molecule and 9.0 (2) and 9.6 (2)° in the other. The planes of the amide groups are inclined at dihedral angles of 83.4 (1) and 87.4 (1)° in the two mol­ecules. In the crystal, mol­ecules are linked into a chain by inter­molecular N—H⋯O hydrogen bonds. International Union of Crystallography 2011-08-11 /pmc/articles/PMC3200632/ /pubmed/22058926 http://dx.doi.org/10.1107/S1600536811031333 Text en © Rodrigues et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rodrigues, Vinola Z.
Foro, Sabine
Gowda, B. Thimme
N,N′-Bis(3-chloro­phen­yl)malonamide
title N,N′-Bis(3-chloro­phen­yl)malonamide
title_full N,N′-Bis(3-chloro­phen­yl)malonamide
title_fullStr N,N′-Bis(3-chloro­phen­yl)malonamide
title_full_unstemmed N,N′-Bis(3-chloro­phen­yl)malonamide
title_short N,N′-Bis(3-chloro­phen­yl)malonamide
title_sort n,n′-bis(3-chloro­phen­yl)malonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200632/
https://www.ncbi.nlm.nih.gov/pubmed/22058926
http://dx.doi.org/10.1107/S1600536811031333
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AT forosabine nnbis3chlorophenylmalonamide
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