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Diaqua­bis­(4-bromo­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))manganese(II)

In the crystal structure of the title Mn(II) complex, [Mn(C(7)H(4)BrO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Mn(II) cation is located on an inversion center and coordinated by two diethyl­nicotinamide (DENA) ligands, two 4-bromo­benzoate (PBB) anions and two water mol­ecules in a distorted octa­...

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Detalles Bibliográficos
Autores principales: Necefoğlu, Hacali, Özbek, Füreya Elif, Öztürk, Vijdan, Adıgüzel, Vedat, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200634/
https://www.ncbi.nlm.nih.gov/pubmed/22064749
http://dx.doi.org/10.1107/S1600536811031412
Descripción
Sumario:In the crystal structure of the title Mn(II) complex, [Mn(C(7)H(4)BrO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Mn(II) cation is located on an inversion center and coordinated by two diethyl­nicotinamide (DENA) ligands, two 4-bromo­benzoate (PBB) anions and two water mol­ecules in a distorted octa­hedral geometry. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 3.25 (14)°. In the mol­ecule, the pyridine ring and the benzene ring are oriented at a dihedral angle of 77.24 (5)°. In the crystal, inter­molecular C—H⋯O hydrogen bonds link the mol­ecules into a two-dimensional network. Weak inter­molecular C—H⋯O hydrogen bonds and π–π inter­actions between the pyridine rings of neighbouring mol­ecules [centroid–centroid distance = 3.537 (1) Å] further consolidate the crystal packing.