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Diaqua­bis­(4-bromo­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))manganese(II)

In the crystal structure of the title Mn(II) complex, [Mn(C(7)H(4)BrO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Mn(II) cation is located on an inversion center and coordinated by two diethyl­nicotinamide (DENA) ligands, two 4-bromo­benzoate (PBB) anions and two water mol­ecules in a distorted octa­...

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Autores principales: Necefoğlu, Hacali, Özbek, Füreya Elif, Öztürk, Vijdan, Adıgüzel, Vedat, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200634/
https://www.ncbi.nlm.nih.gov/pubmed/22064749
http://dx.doi.org/10.1107/S1600536811031412
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author Necefoğlu, Hacali
Özbek, Füreya Elif
Öztürk, Vijdan
Adıgüzel, Vedat
Hökelek, Tuncer
author_facet Necefoğlu, Hacali
Özbek, Füreya Elif
Öztürk, Vijdan
Adıgüzel, Vedat
Hökelek, Tuncer
author_sort Necefoğlu, Hacali
collection PubMed
description In the crystal structure of the title Mn(II) complex, [Mn(C(7)H(4)BrO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Mn(II) cation is located on an inversion center and coordinated by two diethyl­nicotinamide (DENA) ligands, two 4-bromo­benzoate (PBB) anions and two water mol­ecules in a distorted octa­hedral geometry. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 3.25 (14)°. In the mol­ecule, the pyridine ring and the benzene ring are oriented at a dihedral angle of 77.24 (5)°. In the crystal, inter­molecular C—H⋯O hydrogen bonds link the mol­ecules into a two-dimensional network. Weak inter­molecular C—H⋯O hydrogen bonds and π–π inter­actions between the pyridine rings of neighbouring mol­ecules [centroid–centroid distance = 3.537 (1) Å] further consolidate the crystal packing.
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spelling pubmed-32006342011-11-06 Diaqua­bis­(4-bromo­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))manganese(II) Necefoğlu, Hacali Özbek, Füreya Elif Öztürk, Vijdan Adıgüzel, Vedat Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title Mn(II) complex, [Mn(C(7)H(4)BrO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Mn(II) cation is located on an inversion center and coordinated by two diethyl­nicotinamide (DENA) ligands, two 4-bromo­benzoate (PBB) anions and two water mol­ecules in a distorted octa­hedral geometry. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 3.25 (14)°. In the mol­ecule, the pyridine ring and the benzene ring are oriented at a dihedral angle of 77.24 (5)°. In the crystal, inter­molecular C—H⋯O hydrogen bonds link the mol­ecules into a two-dimensional network. Weak inter­molecular C—H⋯O hydrogen bonds and π–π inter­actions between the pyridine rings of neighbouring mol­ecules [centroid–centroid distance = 3.537 (1) Å] further consolidate the crystal packing. International Union of Crystallography 2011-08-06 /pmc/articles/PMC3200634/ /pubmed/22064749 http://dx.doi.org/10.1107/S1600536811031412 Text en © Necefoğlu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Necefoğlu, Hacali
Özbek, Füreya Elif
Öztürk, Vijdan
Adıgüzel, Vedat
Hökelek, Tuncer
Diaqua­bis­(4-bromo­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))manganese(II)
title Diaqua­bis­(4-bromo­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))manganese(II)
title_full Diaqua­bis­(4-bromo­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))manganese(II)
title_fullStr Diaqua­bis­(4-bromo­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))manganese(II)
title_full_unstemmed Diaqua­bis­(4-bromo­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))manganese(II)
title_short Diaqua­bis­(4-bromo­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))manganese(II)
title_sort diaqua­bis­(4-bromo­benzoato-κo)bis­(n,n-diethyl­nicotinamide-κn (1))manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200634/
https://www.ncbi.nlm.nih.gov/pubmed/22064749
http://dx.doi.org/10.1107/S1600536811031412
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