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Diaquabis(4-bromobenzoato-κO)bis(N,N-diethylnicotinamide-κN (1))manganese(II)
In the crystal structure of the title Mn(II) complex, [Mn(C(7)H(4)BrO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Mn(II) cation is located on an inversion center and coordinated by two diethylnicotinamide (DENA) ligands, two 4-bromobenzoate (PBB) anions and two water molecules in a distorted octa...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200634/ https://www.ncbi.nlm.nih.gov/pubmed/22064749 http://dx.doi.org/10.1107/S1600536811031412 |
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author | Necefoğlu, Hacali Özbek, Füreya Elif Öztürk, Vijdan Adıgüzel, Vedat Hökelek, Tuncer |
author_facet | Necefoğlu, Hacali Özbek, Füreya Elif Öztürk, Vijdan Adıgüzel, Vedat Hökelek, Tuncer |
author_sort | Necefoğlu, Hacali |
collection | PubMed |
description | In the crystal structure of the title Mn(II) complex, [Mn(C(7)H(4)BrO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Mn(II) cation is located on an inversion center and coordinated by two diethylnicotinamide (DENA) ligands, two 4-bromobenzoate (PBB) anions and two water molecules in a distorted octahedral geometry. The dihedral angle between the carboxylate group and the adjacent benzene ring is 3.25 (14)°. In the molecule, the pyridine ring and the benzene ring are oriented at a dihedral angle of 77.24 (5)°. In the crystal, intermolecular C—H⋯O hydrogen bonds link the molecules into a two-dimensional network. Weak intermolecular C—H⋯O hydrogen bonds and π–π interactions between the pyridine rings of neighbouring molecules [centroid–centroid distance = 3.537 (1) Å] further consolidate the crystal packing. |
format | Online Article Text |
id | pubmed-3200634 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32006342011-11-06 Diaquabis(4-bromobenzoato-κO)bis(N,N-diethylnicotinamide-κN (1))manganese(II) Necefoğlu, Hacali Özbek, Füreya Elif Öztürk, Vijdan Adıgüzel, Vedat Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title Mn(II) complex, [Mn(C(7)H(4)BrO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Mn(II) cation is located on an inversion center and coordinated by two diethylnicotinamide (DENA) ligands, two 4-bromobenzoate (PBB) anions and two water molecules in a distorted octahedral geometry. The dihedral angle between the carboxylate group and the adjacent benzene ring is 3.25 (14)°. In the molecule, the pyridine ring and the benzene ring are oriented at a dihedral angle of 77.24 (5)°. In the crystal, intermolecular C—H⋯O hydrogen bonds link the molecules into a two-dimensional network. Weak intermolecular C—H⋯O hydrogen bonds and π–π interactions between the pyridine rings of neighbouring molecules [centroid–centroid distance = 3.537 (1) Å] further consolidate the crystal packing. International Union of Crystallography 2011-08-06 /pmc/articles/PMC3200634/ /pubmed/22064749 http://dx.doi.org/10.1107/S1600536811031412 Text en © Necefoğlu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Necefoğlu, Hacali Özbek, Füreya Elif Öztürk, Vijdan Adıgüzel, Vedat Hökelek, Tuncer Diaquabis(4-bromobenzoato-κO)bis(N,N-diethylnicotinamide-κN (1))manganese(II) |
title | Diaquabis(4-bromobenzoato-κO)bis(N,N-diethylnicotinamide-κN
(1))manganese(II) |
title_full | Diaquabis(4-bromobenzoato-κO)bis(N,N-diethylnicotinamide-κN
(1))manganese(II) |
title_fullStr | Diaquabis(4-bromobenzoato-κO)bis(N,N-diethylnicotinamide-κN
(1))manganese(II) |
title_full_unstemmed | Diaquabis(4-bromobenzoato-κO)bis(N,N-diethylnicotinamide-κN
(1))manganese(II) |
title_short | Diaquabis(4-bromobenzoato-κO)bis(N,N-diethylnicotinamide-κN
(1))manganese(II) |
title_sort | diaquabis(4-bromobenzoato-κo)bis(n,n-diethylnicotinamide-κn
(1))manganese(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200634/ https://www.ncbi.nlm.nih.gov/pubmed/22064749 http://dx.doi.org/10.1107/S1600536811031412 |
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