Di-μ-chlorido-bis­{[4-amino-3,5-bis­(2-pyrid­yl)-4H-1,2,4-triazole-κN (1)]chloridomercury(II)}

In the centrosymmetric binuclear title complex, [Hg(2)Cl(4)(C(12)H(10)N(6))(2)], the Hg(II) ion is five-coordinated by two N atoms and three chloride ions with a distorted square-pyramidal geometry. In the complex, there is an intra­molecular N—H⋯N hydrogen bond. In the crystal, the binuclear units...

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Detalles Bibliográficos
Autores principales: Guo, Jian, Tang, Min, Chen, Jing, Li, Cheng-Peng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200639/
https://www.ncbi.nlm.nih.gov/pubmed/22058836
http://dx.doi.org/10.1107/S1600536811029886
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author Guo, Jian
Tang, Min
Chen, Jing
Li, Cheng-Peng
author_facet Guo, Jian
Tang, Min
Chen, Jing
Li, Cheng-Peng
author_sort Guo, Jian
collection PubMed
description In the centrosymmetric binuclear title complex, [Hg(2)Cl(4)(C(12)H(10)N(6))(2)], the Hg(II) ion is five-coordinated by two N atoms and three chloride ions with a distorted square-pyramidal geometry. In the complex, there is an intra­molecular N—H⋯N hydrogen bond. In the crystal, the binuclear units are connected by inter­molecular N—H⋯Cl hydrogen bonds, as well as π–π stacking inter­actions [centroid–centroid distances = 3.526 (2) and 3.696 (2) Å], forming a two-dimensional layered structure parallel to (010).
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spelling pubmed-32006392011-11-06 Di-μ-chlorido-bis­{[4-amino-3,5-bis­(2-pyrid­yl)-4H-1,2,4-triazole-κN (1)]chloridomercury(II)} Guo, Jian Tang, Min Chen, Jing Li, Cheng-Peng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric binuclear title complex, [Hg(2)Cl(4)(C(12)H(10)N(6))(2)], the Hg(II) ion is five-coordinated by two N atoms and three chloride ions with a distorted square-pyramidal geometry. In the complex, there is an intra­molecular N—H⋯N hydrogen bond. In the crystal, the binuclear units are connected by inter­molecular N—H⋯Cl hydrogen bonds, as well as π–π stacking inter­actions [centroid–centroid distances = 3.526 (2) and 3.696 (2) Å], forming a two-dimensional layered structure parallel to (010). International Union of Crystallography 2011-08-02 /pmc/articles/PMC3200639/ /pubmed/22058836 http://dx.doi.org/10.1107/S1600536811029886 Text en © Guo et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guo, Jian
Tang, Min
Chen, Jing
Li, Cheng-Peng
Di-μ-chlorido-bis­{[4-amino-3,5-bis­(2-pyrid­yl)-4H-1,2,4-triazole-κN (1)]chloridomercury(II)}
title Di-μ-chlorido-bis­{[4-amino-3,5-bis­(2-pyrid­yl)-4H-1,2,4-triazole-κN (1)]chloridomercury(II)}
title_full Di-μ-chlorido-bis­{[4-amino-3,5-bis­(2-pyrid­yl)-4H-1,2,4-triazole-κN (1)]chloridomercury(II)}
title_fullStr Di-μ-chlorido-bis­{[4-amino-3,5-bis­(2-pyrid­yl)-4H-1,2,4-triazole-κN (1)]chloridomercury(II)}
title_full_unstemmed Di-μ-chlorido-bis­{[4-amino-3,5-bis­(2-pyrid­yl)-4H-1,2,4-triazole-κN (1)]chloridomercury(II)}
title_short Di-μ-chlorido-bis­{[4-amino-3,5-bis­(2-pyrid­yl)-4H-1,2,4-triazole-κN (1)]chloridomercury(II)}
title_sort di-μ-chlorido-bis­{[4-amino-3,5-bis­(2-pyrid­yl)-4h-1,2,4-triazole-κn (1)]chloridomercury(ii)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200639/
https://www.ncbi.nlm.nih.gov/pubmed/22058836
http://dx.doi.org/10.1107/S1600536811029886
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