N,N′-Dibenzyl-N′′-(2-chloro­acet­yl)-N,N′-dimethyl­phospho­ric triamide

In the title mol­ecule, C(18)H(23)ClN(3)O(2)P, the P atom is bonded in a distorted tetra­hedral environment. The P=O and N—H groups are syn with respect to each other. The angles at the tertiary N atoms confirm their sp (2) character. In the crystal, pairs of inter­molecular P=O⋯H—N hydrogen bonds f...

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Detalles Bibliográficos
Autores principales: Pourayoubi, Mehrdad, Keikha, Mojtaba, Nečas, Marek
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200640/
https://www.ncbi.nlm.nih.gov/pubmed/22059012
http://dx.doi.org/10.1107/S1600536811033204
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author Pourayoubi, Mehrdad
Keikha, Mojtaba
Nečas, Marek
author_facet Pourayoubi, Mehrdad
Keikha, Mojtaba
Nečas, Marek
author_sort Pourayoubi, Mehrdad
collection PubMed
description In the title mol­ecule, C(18)H(23)ClN(3)O(2)P, the P atom is bonded in a distorted tetra­hedral environment. The P=O and N—H groups are syn with respect to each other. The angles at the tertiary N atoms confirm their sp (2) character. In the crystal, pairs of inter­molecular P=O⋯H—N hydrogen bonds form centrosymmetric dimers.
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spelling pubmed-32006402011-11-06 N,N′-Dibenzyl-N′′-(2-chloro­acet­yl)-N,N′-dimethyl­phospho­ric triamide Pourayoubi, Mehrdad Keikha, Mojtaba Nečas, Marek Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(18)H(23)ClN(3)O(2)P, the P atom is bonded in a distorted tetra­hedral environment. The P=O and N—H groups are syn with respect to each other. The angles at the tertiary N atoms confirm their sp (2) character. In the crystal, pairs of inter­molecular P=O⋯H—N hydrogen bonds form centrosymmetric dimers. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200640/ /pubmed/22059012 http://dx.doi.org/10.1107/S1600536811033204 Text en © Pourayoubi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pourayoubi, Mehrdad
Keikha, Mojtaba
Nečas, Marek
N,N′-Dibenzyl-N′′-(2-chloro­acet­yl)-N,N′-dimethyl­phospho­ric triamide
title N,N′-Dibenzyl-N′′-(2-chloro­acet­yl)-N,N′-dimethyl­phospho­ric triamide
title_full N,N′-Dibenzyl-N′′-(2-chloro­acet­yl)-N,N′-dimethyl­phospho­ric triamide
title_fullStr N,N′-Dibenzyl-N′′-(2-chloro­acet­yl)-N,N′-dimethyl­phospho­ric triamide
title_full_unstemmed N,N′-Dibenzyl-N′′-(2-chloro­acet­yl)-N,N′-dimethyl­phospho­ric triamide
title_short N,N′-Dibenzyl-N′′-(2-chloro­acet­yl)-N,N′-dimethyl­phospho­ric triamide
title_sort n,n′-dibenzyl-n′′-(2-chloro­acet­yl)-n,n′-dimethyl­phospho­ric triamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200640/
https://www.ncbi.nlm.nih.gov/pubmed/22059012
http://dx.doi.org/10.1107/S1600536811033204
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AT necasmarek nndibenzyln2chloroacetylnndimethylphosphorictriamide

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