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N-(2,6-Difluoro­benzo­yl)-P,P-bis­(pyrrolidin-1-yl)phosphinic amide

The phosphoryl and carbonyl groups in the title compound, C(15)H(20)F(2)N(3)O(2)P, are anti with respect to each other (but the P- and C-groups are separated by another atom) and the P atom is in a tetra­hedral coordination environment. Two C atoms in one of the pyrrolidinyl fragments are disordered...

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Detalles Bibliográficos
Autores principales: Pourayoubi, Mehrdad, Tarahhomi, Atekeh, Rheingold, Arnold L., Golen, James A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200646/
https://www.ncbi.nlm.nih.gov/pubmed/22059015
http://dx.doi.org/10.1107/S1600536811033216
Descripción
Sumario:The phosphoryl and carbonyl groups in the title compound, C(15)H(20)F(2)N(3)O(2)P, are anti with respect to each other (but the P- and C-groups are separated by another atom) and the P atom is in a tetra­hedral coordination environment. Two C atoms in one of the pyrrolidinyl fragments are disordered over two sets of sites with occupancies of 0.746 (8) and 0.254 (8). The environments of the pyrrolidinyl N atoms show a slight deviation from planarity and none of the three N atoms is involved in any hydrogen bond as an acceptor. In the crystal, pairs of inter­molecular N—H⋯O hydrogen bonds form inversion dimers.