Cargando…
N-(2,6-Difluorobenzoyl)-P,P-bis(pyrrolidin-1-yl)phosphinic amide
The phosphoryl and carbonyl groups in the title compound, C(15)H(20)F(2)N(3)O(2)P, are anti with respect to each other (but the P- and C-groups are separated by another atom) and the P atom is in a tetrahedral coordination environment. Two C atoms in one of the pyrrolidinyl fragments are disordered...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200646/ https://www.ncbi.nlm.nih.gov/pubmed/22059015 http://dx.doi.org/10.1107/S1600536811033216 |
_version_ | 1782214717528342528 |
---|---|
author | Pourayoubi, Mehrdad Tarahhomi, Atekeh Rheingold, Arnold L. Golen, James A. |
author_facet | Pourayoubi, Mehrdad Tarahhomi, Atekeh Rheingold, Arnold L. Golen, James A. |
author_sort | Pourayoubi, Mehrdad |
collection | PubMed |
description | The phosphoryl and carbonyl groups in the title compound, C(15)H(20)F(2)N(3)O(2)P, are anti with respect to each other (but the P- and C-groups are separated by another atom) and the P atom is in a tetrahedral coordination environment. Two C atoms in one of the pyrrolidinyl fragments are disordered over two sets of sites with occupancies of 0.746 (8) and 0.254 (8). The environments of the pyrrolidinyl N atoms show a slight deviation from planarity and none of the three N atoms is involved in any hydrogen bond as an acceptor. In the crystal, pairs of intermolecular N—H⋯O hydrogen bonds form inversion dimers. |
format | Online Article Text |
id | pubmed-3200646 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32006462011-11-06 N-(2,6-Difluorobenzoyl)-P,P-bis(pyrrolidin-1-yl)phosphinic amide Pourayoubi, Mehrdad Tarahhomi, Atekeh Rheingold, Arnold L. Golen, James A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The phosphoryl and carbonyl groups in the title compound, C(15)H(20)F(2)N(3)O(2)P, are anti with respect to each other (but the P- and C-groups are separated by another atom) and the P atom is in a tetrahedral coordination environment. Two C atoms in one of the pyrrolidinyl fragments are disordered over two sets of sites with occupancies of 0.746 (8) and 0.254 (8). The environments of the pyrrolidinyl N atoms show a slight deviation from planarity and none of the three N atoms is involved in any hydrogen bond as an acceptor. In the crystal, pairs of intermolecular N—H⋯O hydrogen bonds form inversion dimers. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200646/ /pubmed/22059015 http://dx.doi.org/10.1107/S1600536811033216 Text en © Pourayoubi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Pourayoubi, Mehrdad Tarahhomi, Atekeh Rheingold, Arnold L. Golen, James A. N-(2,6-Difluorobenzoyl)-P,P-bis(pyrrolidin-1-yl)phosphinic amide |
title |
N-(2,6-Difluorobenzoyl)-P,P-bis(pyrrolidin-1-yl)phosphinic amide |
title_full |
N-(2,6-Difluorobenzoyl)-P,P-bis(pyrrolidin-1-yl)phosphinic amide |
title_fullStr |
N-(2,6-Difluorobenzoyl)-P,P-bis(pyrrolidin-1-yl)phosphinic amide |
title_full_unstemmed |
N-(2,6-Difluorobenzoyl)-P,P-bis(pyrrolidin-1-yl)phosphinic amide |
title_short |
N-(2,6-Difluorobenzoyl)-P,P-bis(pyrrolidin-1-yl)phosphinic amide |
title_sort | n-(2,6-difluorobenzoyl)-p,p-bis(pyrrolidin-1-yl)phosphinic amide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200646/ https://www.ncbi.nlm.nih.gov/pubmed/22059015 http://dx.doi.org/10.1107/S1600536811033216 |
work_keys_str_mv | AT pourayoubimehrdad n26difluorobenzoylppbispyrrolidin1ylphosphinicamide AT tarahhomiatekeh n26difluorobenzoylppbispyrrolidin1ylphosphinicamide AT rheingoldarnoldl n26difluorobenzoylppbispyrrolidin1ylphosphinicamide AT golenjamesa n26difluorobenzoylppbispyrrolidin1ylphosphinicamide |