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N-(2,6-Difluoro­benzo­yl)-P,P-bis­(pyrrolidin-1-yl)phosphinic amide

The phosphoryl and carbonyl groups in the title compound, C(15)H(20)F(2)N(3)O(2)P, are anti with respect to each other (but the P- and C-groups are separated by another atom) and the P atom is in a tetra­hedral coordination environment. Two C atoms in one of the pyrrolidinyl fragments are disordered...

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Autores principales: Pourayoubi, Mehrdad, Tarahhomi, Atekeh, Rheingold, Arnold L., Golen, James A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200646/
https://www.ncbi.nlm.nih.gov/pubmed/22059015
http://dx.doi.org/10.1107/S1600536811033216
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author Pourayoubi, Mehrdad
Tarahhomi, Atekeh
Rheingold, Arnold L.
Golen, James A.
author_facet Pourayoubi, Mehrdad
Tarahhomi, Atekeh
Rheingold, Arnold L.
Golen, James A.
author_sort Pourayoubi, Mehrdad
collection PubMed
description The phosphoryl and carbonyl groups in the title compound, C(15)H(20)F(2)N(3)O(2)P, are anti with respect to each other (but the P- and C-groups are separated by another atom) and the P atom is in a tetra­hedral coordination environment. Two C atoms in one of the pyrrolidinyl fragments are disordered over two sets of sites with occupancies of 0.746 (8) and 0.254 (8). The environments of the pyrrolidinyl N atoms show a slight deviation from planarity and none of the three N atoms is involved in any hydrogen bond as an acceptor. In the crystal, pairs of inter­molecular N—H⋯O hydrogen bonds form inversion dimers.
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spelling pubmed-32006462011-11-06 N-(2,6-Difluoro­benzo­yl)-P,P-bis­(pyrrolidin-1-yl)phosphinic amide Pourayoubi, Mehrdad Tarahhomi, Atekeh Rheingold, Arnold L. Golen, James A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The phosphoryl and carbonyl groups in the title compound, C(15)H(20)F(2)N(3)O(2)P, are anti with respect to each other (but the P- and C-groups are separated by another atom) and the P atom is in a tetra­hedral coordination environment. Two C atoms in one of the pyrrolidinyl fragments are disordered over two sets of sites with occupancies of 0.746 (8) and 0.254 (8). The environments of the pyrrolidinyl N atoms show a slight deviation from planarity and none of the three N atoms is involved in any hydrogen bond as an acceptor. In the crystal, pairs of inter­molecular N—H⋯O hydrogen bonds form inversion dimers. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200646/ /pubmed/22059015 http://dx.doi.org/10.1107/S1600536811033216 Text en © Pourayoubi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pourayoubi, Mehrdad
Tarahhomi, Atekeh
Rheingold, Arnold L.
Golen, James A.
N-(2,6-Difluoro­benzo­yl)-P,P-bis­(pyrrolidin-1-yl)phosphinic amide
title N-(2,6-Difluoro­benzo­yl)-P,P-bis­(pyrrolidin-1-yl)phosphinic amide
title_full N-(2,6-Difluoro­benzo­yl)-P,P-bis­(pyrrolidin-1-yl)phosphinic amide
title_fullStr N-(2,6-Difluoro­benzo­yl)-P,P-bis­(pyrrolidin-1-yl)phosphinic amide
title_full_unstemmed N-(2,6-Difluoro­benzo­yl)-P,P-bis­(pyrrolidin-1-yl)phosphinic amide
title_short N-(2,6-Difluoro­benzo­yl)-P,P-bis­(pyrrolidin-1-yl)phosphinic amide
title_sort n-(2,6-difluoro­benzo­yl)-p,p-bis­(pyrrolidin-1-yl)phosphinic amide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200646/
https://www.ncbi.nlm.nih.gov/pubmed/22059015
http://dx.doi.org/10.1107/S1600536811033216
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