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catena-Poly[[bis(N,N-dimethylformamide-κO)zinc]-μ(2)-oxalato-κ(4) O (1),O (2):O (1′),O (2′)]
In the crystal structure of the title compound, [Zn(C(2)O(4))(C(3)H(7)NO)(2)](n), the Zn(II) ion is situated on a twofold rotation axis and has a distorted octahedral coordination geometry defined by the O atoms of two dimethylformamide molecules and four O atoms of two bidentate oxalate ligands....
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200650/ https://www.ncbi.nlm.nih.gov/pubmed/22058834 http://dx.doi.org/10.1107/S1600536811030479 |
| _version_ | 1782214718438506496 |
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| author | Lee, Ju Eun Lee, Hong-In |
| author_facet | Lee, Ju Eun Lee, Hong-In |
| author_sort | Lee, Ju Eun |
| collection | PubMed |
| description | In the crystal structure of the title compound, [Zn(C(2)O(4))(C(3)H(7)NO)(2)](n), the Zn(II) ion is situated on a twofold rotation axis and has a distorted octahedral coordination geometry defined by the O atoms of two dimethylformamide molecules and four O atoms of two bidentate oxalate ligands. The oxalate anion is located on an inversion centre and bridges two metal ions, resulting in a polymeric structure with infinite zigzag chains extending parallel to [010]. |
| format | Online Article Text |
| id | pubmed-3200650 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32006502011-11-06 catena-Poly[[bis(N,N-dimethylformamide-κO)zinc]-μ(2)-oxalato-κ(4) O (1),O (2):O (1′),O (2′)] Lee, Ju Eun Lee, Hong-In Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Zn(C(2)O(4))(C(3)H(7)NO)(2)](n), the Zn(II) ion is situated on a twofold rotation axis and has a distorted octahedral coordination geometry defined by the O atoms of two dimethylformamide molecules and four O atoms of two bidentate oxalate ligands. The oxalate anion is located on an inversion centre and bridges two metal ions, resulting in a polymeric structure with infinite zigzag chains extending parallel to [010]. International Union of Crystallography 2011-08-02 /pmc/articles/PMC3200650/ /pubmed/22058834 http://dx.doi.org/10.1107/S1600536811030479 Text en © Lee and Lee 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Lee, Ju Eun Lee, Hong-In catena-Poly[[bis(N,N-dimethylformamide-κO)zinc]-μ(2)-oxalato-κ(4) O (1),O (2):O (1′),O (2′)] |
| title |
catena-Poly[[bis(N,N-dimethylformamide-κO)zinc]-μ(2)-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)] |
| title_full |
catena-Poly[[bis(N,N-dimethylformamide-κO)zinc]-μ(2)-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)] |
| title_fullStr |
catena-Poly[[bis(N,N-dimethylformamide-κO)zinc]-μ(2)-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)] |
| title_full_unstemmed |
catena-Poly[[bis(N,N-dimethylformamide-κO)zinc]-μ(2)-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)] |
| title_short |
catena-Poly[[bis(N,N-dimethylformamide-κO)zinc]-μ(2)-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)] |
| title_sort | catena-poly[[bis(n,n-dimethylformamide-κo)zinc]-μ(2)-oxalato-κ(4)
o
(1),o
(2):o
(1′),o
(2′)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200650/ https://www.ncbi.nlm.nih.gov/pubmed/22058834 http://dx.doi.org/10.1107/S1600536811030479 |
| work_keys_str_mv | AT leejueun catenapolybisnndimethylformamidekozincm2oxalatok4o1o2o1o2 AT leehongin catenapolybisnndimethylformamidekozincm2oxalatok4o1o2o1o2 |