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N′-(3,5-Dibromo-2-hy­droxy­benzyl­idene)-4-nitro­benzohydrazide methanol monosolvate

The title compound, C(14)H(9)Br(2)N(3)O(4)·CH(4)O, was obtained as the product of the reaction of 3,5-dibromo­salicyl­aldehyde with 4-nitro­benzohydrazide in methanol. The benzohydrazide mol­ecule is nearly planar, with a maximum deviation of 0.126 (2) Å. The mean planes of the two benzene rings mak...

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Detalles Bibliográficos
Autores principales: Zhou, Xin, Gao, Shu-Tao, Ma, Jing-Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200651/
https://www.ncbi.nlm.nih.gov/pubmed/22065140
http://dx.doi.org/10.1107/S1600536811031187
Descripción
Sumario:The title compound, C(14)H(9)Br(2)N(3)O(4)·CH(4)O, was obtained as the product of the reaction of 3,5-dibromo­salicyl­aldehyde with 4-nitro­benzohydrazide in methanol. The benzohydrazide mol­ecule is nearly planar, with a maximum deviation of 0.126 (2) Å. The mean planes of the two benzene rings make a dihedral angle of 9.3 (3)°. Intra­molecular O—H⋯N and O—H⋯Br inter­actions are observed in the benzohydrazide mol­ecule. In the crystal, pairs of adjacent benzohydrazide mol­ecules are linked by two methanol mol­ecules through inter­molecular O—H⋯O and N—H⋯O hydrogen bonds, forming a dimer.