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N′-(3,5-Dibromo-2-hydroxybenzylidene)-4-nitrobenzohydrazide methanol monosolvate
The title compound, C(14)H(9)Br(2)N(3)O(4)·CH(4)O, was obtained as the product of the reaction of 3,5-dibromosalicylaldehyde with 4-nitrobenzohydrazide in methanol. The benzohydrazide molecule is nearly planar, with a maximum deviation of 0.126 (2) Å. The mean planes of the two benzene rings mak...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200651/ https://www.ncbi.nlm.nih.gov/pubmed/22065140 http://dx.doi.org/10.1107/S1600536811031187 |
Sumario: | The title compound, C(14)H(9)Br(2)N(3)O(4)·CH(4)O, was obtained as the product of the reaction of 3,5-dibromosalicylaldehyde with 4-nitrobenzohydrazide in methanol. The benzohydrazide molecule is nearly planar, with a maximum deviation of 0.126 (2) Å. The mean planes of the two benzene rings make a dihedral angle of 9.3 (3)°. Intramolecular O—H⋯N and O—H⋯Br interactions are observed in the benzohydrazide molecule. In the crystal, pairs of adjacent benzohydrazide molecules are linked by two methanol molecules through intermolecular O—H⋯O and N—H⋯O hydrogen bonds, forming a dimer. |
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