N′-(3,5-Dibromo-2-hy­droxy­benzyl­idene)-4-nitro­benzohydrazide methanol monosolvate

The title compound, C(14)H(9)Br(2)N(3)O(4)·CH(4)O, was obtained as the product of the reaction of 3,5-dibromo­salicyl­aldehyde with 4-nitro­benzohydrazide in methanol. The benzohydrazide mol­ecule is nearly planar, with a maximum deviation of 0.126 (2) Å. The mean planes of the two benzene rings mak...

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Detalles Bibliográficos
Autores principales: Zhou, Xin, Gao, Shu-Tao, Ma, Jing-Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200651/
https://www.ncbi.nlm.nih.gov/pubmed/22065140
http://dx.doi.org/10.1107/S1600536811031187
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author Zhou, Xin
Gao, Shu-Tao
Ma, Jing-Jun
author_facet Zhou, Xin
Gao, Shu-Tao
Ma, Jing-Jun
author_sort Zhou, Xin
collection PubMed
description The title compound, C(14)H(9)Br(2)N(3)O(4)·CH(4)O, was obtained as the product of the reaction of 3,5-dibromo­salicyl­aldehyde with 4-nitro­benzohydrazide in methanol. The benzohydrazide mol­ecule is nearly planar, with a maximum deviation of 0.126 (2) Å. The mean planes of the two benzene rings make a dihedral angle of 9.3 (3)°. Intra­molecular O—H⋯N and O—H⋯Br inter­actions are observed in the benzohydrazide mol­ecule. In the crystal, pairs of adjacent benzohydrazide mol­ecules are linked by two methanol mol­ecules through inter­molecular O—H⋯O and N—H⋯O hydrogen bonds, forming a dimer.
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spelling pubmed-32006512011-11-06 N′-(3,5-Dibromo-2-hy­droxy­benzyl­idene)-4-nitro­benzohydrazide methanol monosolvate Zhou, Xin Gao, Shu-Tao Ma, Jing-Jun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(9)Br(2)N(3)O(4)·CH(4)O, was obtained as the product of the reaction of 3,5-dibromo­salicyl­aldehyde with 4-nitro­benzohydrazide in methanol. The benzohydrazide mol­ecule is nearly planar, with a maximum deviation of 0.126 (2) Å. The mean planes of the two benzene rings make a dihedral angle of 9.3 (3)°. Intra­molecular O—H⋯N and O—H⋯Br inter­actions are observed in the benzohydrazide mol­ecule. In the crystal, pairs of adjacent benzohydrazide mol­ecules are linked by two methanol mol­ecules through inter­molecular O—H⋯O and N—H⋯O hydrogen bonds, forming a dimer. International Union of Crystallography 2011-08-11 /pmc/articles/PMC3200651/ /pubmed/22065140 http://dx.doi.org/10.1107/S1600536811031187 Text en © Zhou et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhou, Xin
Gao, Shu-Tao
Ma, Jing-Jun
N′-(3,5-Dibromo-2-hy­droxy­benzyl­idene)-4-nitro­benzohydrazide methanol monosolvate
title N′-(3,5-Dibromo-2-hy­droxy­benzyl­idene)-4-nitro­benzohydrazide methanol monosolvate
title_full N′-(3,5-Dibromo-2-hy­droxy­benzyl­idene)-4-nitro­benzohydrazide methanol monosolvate
title_fullStr N′-(3,5-Dibromo-2-hy­droxy­benzyl­idene)-4-nitro­benzohydrazide methanol monosolvate
title_full_unstemmed N′-(3,5-Dibromo-2-hy­droxy­benzyl­idene)-4-nitro­benzohydrazide methanol monosolvate
title_short N′-(3,5-Dibromo-2-hy­droxy­benzyl­idene)-4-nitro­benzohydrazide methanol monosolvate
title_sort n′-(3,5-dibromo-2-hy­droxy­benzyl­idene)-4-nitro­benzohydrazide methanol monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200651/
https://www.ncbi.nlm.nih.gov/pubmed/22065140
http://dx.doi.org/10.1107/S1600536811031187
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AT majingjun n35dibromo2hydroxybenzylidene4nitrobenzohydrazidemethanolmonosolvate

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