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Aqua{6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}zinc
The mononuclear zinc title complex, [Zn(C(20)H(22)N(2)O(4))(H(2)O)], was obtained by the reaction of 3-ethoxysalicylaldehyde, ethane-1,2-diamine, and zinc acetate in methanol. The Zn atom is five-coordinated by two phenolate O and two imine N atoms of the tetradentate Schiff base ligand and by on...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200652/ https://www.ncbi.nlm.nih.gov/pubmed/22065396 http://dx.doi.org/10.1107/S1600536811031497 |
| _version_ | 1782214718885199872 |
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| author | Wang, Chen-Yi Wu, Xiang Hu, Juan-Juan Han, Zhi-Ping |
| author_facet | Wang, Chen-Yi Wu, Xiang Hu, Juan-Juan Han, Zhi-Ping |
| author_sort | Wang, Chen-Yi |
| collection | PubMed |
| description | The mononuclear zinc title complex, [Zn(C(20)H(22)N(2)O(4))(H(2)O)], was obtained by the reaction of 3-ethoxysalicylaldehyde, ethane-1,2-diamine, and zinc acetate in methanol. The Zn atom is five-coordinated by two phenolate O and two imine N atoms of the tetradentate Schiff base ligand and by one water O atom, forming a square-pyramidal geometry. In the crystal, pairs of molecules are linked via intermolecular O—H⋯O hydrogen bonds, forming dimers. |
| format | Online Article Text |
| id | pubmed-3200652 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32006522011-11-06 Aqua{6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}zinc Wang, Chen-Yi Wu, Xiang Hu, Juan-Juan Han, Zhi-Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The mononuclear zinc title complex, [Zn(C(20)H(22)N(2)O(4))(H(2)O)], was obtained by the reaction of 3-ethoxysalicylaldehyde, ethane-1,2-diamine, and zinc acetate in methanol. The Zn atom is five-coordinated by two phenolate O and two imine N atoms of the tetradentate Schiff base ligand and by one water O atom, forming a square-pyramidal geometry. In the crystal, pairs of molecules are linked via intermolecular O—H⋯O hydrogen bonds, forming dimers. International Union of Crystallography 2011-08-11 /pmc/articles/PMC3200652/ /pubmed/22065396 http://dx.doi.org/10.1107/S1600536811031497 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wang, Chen-Yi Wu, Xiang Hu, Juan-Juan Han, Zhi-Ping Aqua{6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}zinc |
| title | Aqua{6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}zinc |
| title_full | Aqua{6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}zinc |
| title_fullStr | Aqua{6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}zinc |
| title_full_unstemmed | Aqua{6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}zinc |
| title_short | Aqua{6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}zinc |
| title_sort | aqua{6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}zinc |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200652/ https://www.ncbi.nlm.nih.gov/pubmed/22065396 http://dx.doi.org/10.1107/S1600536811031497 |
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