Cargando…
Bis[μ-N′-(2-methyl-1-oxidopropanylidene)-2-oxidobenzohydrazidato]tetrapyridinetrinickel(II)
The asymmetric unit of the title trinuclear Ni(II) compound, [Ni(3)(C(11)H(11)N(2)O(3))(C(5)H(5)N)(4)], contains two independent molecules which are located on individual inversion centres. The central Ni atom, located on an inversion centre, is coordinated by two pyridine N atoms and is further N,...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200653/ https://www.ncbi.nlm.nih.gov/pubmed/22065471 http://dx.doi.org/10.1107/S1600536811034362 |
_version_ | 1782214719112740864 |
---|---|
author | Chen, Xiao-Hua Xie, Chun-Ling Yang, Ming-Xing Chen, Li-Juan |
author_facet | Chen, Xiao-Hua Xie, Chun-Ling Yang, Ming-Xing Chen, Li-Juan |
author_sort | Chen, Xiao-Hua |
collection | PubMed |
description | The asymmetric unit of the title trinuclear Ni(II) compound, [Ni(3)(C(11)H(11)N(2)O(3))(C(5)H(5)N)(4)], contains two independent molecules which are located on individual inversion centres. The central Ni atom, located on an inversion centre, is coordinated by two pyridine N atoms and is further N,O-chelated by two N-(2-methylpropanoyl)salicyloylhydrazidate anions in an elongated octahedral coordination geometry. The terminal Ni atom is coordinated by a pyridine ligand and is further N,N′,O-chelated by an N-(2-methylpropanoyl)salicyloylhydrazidate anion in a distorted square-planar coordination geometry. Weak intramolecular C—H⋯O hydrogen bonding is observed in the structure. |
format | Online Article Text |
id | pubmed-3200653 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32006532011-11-06 Bis[μ-N′-(2-methyl-1-oxidopropanylidene)-2-oxidobenzohydrazidato]tetrapyridinetrinickel(II) Chen, Xiao-Hua Xie, Chun-Ling Yang, Ming-Xing Chen, Li-Juan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title trinuclear Ni(II) compound, [Ni(3)(C(11)H(11)N(2)O(3))(C(5)H(5)N)(4)], contains two independent molecules which are located on individual inversion centres. The central Ni atom, located on an inversion centre, is coordinated by two pyridine N atoms and is further N,O-chelated by two N-(2-methylpropanoyl)salicyloylhydrazidate anions in an elongated octahedral coordination geometry. The terminal Ni atom is coordinated by a pyridine ligand and is further N,N′,O-chelated by an N-(2-methylpropanoyl)salicyloylhydrazidate anion in a distorted square-planar coordination geometry. Weak intramolecular C—H⋯O hydrogen bonding is observed in the structure. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200653/ /pubmed/22065471 http://dx.doi.org/10.1107/S1600536811034362 Text en © Chen et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Chen, Xiao-Hua Xie, Chun-Ling Yang, Ming-Xing Chen, Li-Juan Bis[μ-N′-(2-methyl-1-oxidopropanylidene)-2-oxidobenzohydrazidato]tetrapyridinetrinickel(II) |
title | Bis[μ-N′-(2-methyl-1-oxidopropanylidene)-2-oxidobenzohydrazidato]tetrapyridinetrinickel(II) |
title_full | Bis[μ-N′-(2-methyl-1-oxidopropanylidene)-2-oxidobenzohydrazidato]tetrapyridinetrinickel(II) |
title_fullStr | Bis[μ-N′-(2-methyl-1-oxidopropanylidene)-2-oxidobenzohydrazidato]tetrapyridinetrinickel(II) |
title_full_unstemmed | Bis[μ-N′-(2-methyl-1-oxidopropanylidene)-2-oxidobenzohydrazidato]tetrapyridinetrinickel(II) |
title_short | Bis[μ-N′-(2-methyl-1-oxidopropanylidene)-2-oxidobenzohydrazidato]tetrapyridinetrinickel(II) |
title_sort | bis[μ-n′-(2-methyl-1-oxidopropanylidene)-2-oxidobenzohydrazidato]tetrapyridinetrinickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200653/ https://www.ncbi.nlm.nih.gov/pubmed/22065471 http://dx.doi.org/10.1107/S1600536811034362 |
work_keys_str_mv | AT chenxiaohua bismn2methyl1oxidopropanylidene2oxidobenzohydrazidatotetrapyridinetrinickelii AT xiechunling bismn2methyl1oxidopropanylidene2oxidobenzohydrazidatotetrapyridinetrinickelii AT yangmingxing bismn2methyl1oxidopropanylidene2oxidobenzohydrazidatotetrapyridinetrinickelii AT chenlijuan bismn2methyl1oxidopropanylidene2oxidobenzohydrazidatotetrapyridinetrinickelii |