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Bis[μ-N′-(2-methyl-1-oxidopropanyl­idene)-2-oxidobenzohydrazidato]tetra­pyridine­trinickel(II)

The asymmetric unit of the title trinuclear Ni(II) compound, [Ni(3)(C(11)H(11)N(2)O(3))(C(5)H(5)N)(4)], contains two independent mol­ecules which are located on individual inversion centres. The central Ni atom, located on an inversion centre, is coordinated by two pyridine N atoms and is further N,...

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Autores principales: Chen, Xiao-Hua, Xie, Chun-Ling, Yang, Ming-Xing, Chen, Li-Juan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200653/
https://www.ncbi.nlm.nih.gov/pubmed/22065471
http://dx.doi.org/10.1107/S1600536811034362
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author Chen, Xiao-Hua
Xie, Chun-Ling
Yang, Ming-Xing
Chen, Li-Juan
author_facet Chen, Xiao-Hua
Xie, Chun-Ling
Yang, Ming-Xing
Chen, Li-Juan
author_sort Chen, Xiao-Hua
collection PubMed
description The asymmetric unit of the title trinuclear Ni(II) compound, [Ni(3)(C(11)H(11)N(2)O(3))(C(5)H(5)N)(4)], contains two independent mol­ecules which are located on individual inversion centres. The central Ni atom, located on an inversion centre, is coordinated by two pyridine N atoms and is further N,O-chelated by two N-(2-methyl­propano­yl)salicyloylhydrazidate anions in an elongated octa­hedral coordination geometry. The terminal Ni atom is coordinated by a pyridine ligand and is further N,N′,O-chelated by an N-(2-methyl­propano­yl)salicyloyl­hydrazidate anion in a distorted square-planar coordination geometry. Weak intra­molecular C—H⋯O hydrogen bonding is observed in the structure.
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spelling pubmed-32006532011-11-06 Bis[μ-N′-(2-methyl-1-oxidopropanyl­idene)-2-oxidobenzohydrazidato]tetra­pyridine­trinickel(II) Chen, Xiao-Hua Xie, Chun-Ling Yang, Ming-Xing Chen, Li-Juan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title trinuclear Ni(II) compound, [Ni(3)(C(11)H(11)N(2)O(3))(C(5)H(5)N)(4)], contains two independent mol­ecules which are located on individual inversion centres. The central Ni atom, located on an inversion centre, is coordinated by two pyridine N atoms and is further N,O-chelated by two N-(2-methyl­propano­yl)salicyloylhydrazidate anions in an elongated octa­hedral coordination geometry. The terminal Ni atom is coordinated by a pyridine ligand and is further N,N′,O-chelated by an N-(2-methyl­propano­yl)salicyloyl­hydrazidate anion in a distorted square-planar coordination geometry. Weak intra­molecular C—H⋯O hydrogen bonding is observed in the structure. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200653/ /pubmed/22065471 http://dx.doi.org/10.1107/S1600536811034362 Text en © Chen et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Xiao-Hua
Xie, Chun-Ling
Yang, Ming-Xing
Chen, Li-Juan
Bis[μ-N′-(2-methyl-1-oxidopropanyl­idene)-2-oxidobenzohydrazidato]tetra­pyridine­trinickel(II)
title Bis[μ-N′-(2-methyl-1-oxidopropanyl­idene)-2-oxidobenzohydrazidato]tetra­pyridine­trinickel(II)
title_full Bis[μ-N′-(2-methyl-1-oxidopropanyl­idene)-2-oxidobenzohydrazidato]tetra­pyridine­trinickel(II)
title_fullStr Bis[μ-N′-(2-methyl-1-oxidopropanyl­idene)-2-oxidobenzohydrazidato]tetra­pyridine­trinickel(II)
title_full_unstemmed Bis[μ-N′-(2-methyl-1-oxidopropanyl­idene)-2-oxidobenzohydrazidato]tetra­pyridine­trinickel(II)
title_short Bis[μ-N′-(2-methyl-1-oxidopropanyl­idene)-2-oxidobenzohydrazidato]tetra­pyridine­trinickel(II)
title_sort bis[μ-n′-(2-methyl-1-oxidopropanyl­idene)-2-oxidobenzohydrazidato]tetra­pyridine­trinickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200653/
https://www.ncbi.nlm.nih.gov/pubmed/22065471
http://dx.doi.org/10.1107/S1600536811034362
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