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(4-Chloro-3-nitrobenzoato)triphenyltin(IV)
In the title compound, [Sn(C(6)H(5))(3)(C(7)H(3)ClNO(4))], the four-coordinate Sn(IV) atom exists in a distorted tetrahedral geometry, formed by a monodentate carboxylate group and three phenyl rings. The conformation is stabilized by an intramolecular C—H⋯O hydrogen bond, which generates an S(5)...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200665/ https://www.ncbi.nlm.nih.gov/pubmed/22065496 http://dx.doi.org/10.1107/S160053681103282X |
| _version_ | 1782214721826455552 |
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| author | Win, Yip-Foo Choong, Chen-Shang Teoh, Siang-Guan Quah, Ching Kheng Fun, Hoong-Kun |
| author_facet | Win, Yip-Foo Choong, Chen-Shang Teoh, Siang-Guan Quah, Ching Kheng Fun, Hoong-Kun |
| author_sort | Win, Yip-Foo |
| collection | PubMed |
| description | In the title compound, [Sn(C(6)H(5))(3)(C(7)H(3)ClNO(4))], the four-coordinate Sn(IV) atom exists in a distorted tetrahedral geometry, formed by a monodentate carboxylate group and three phenyl rings. The conformation is stabilized by an intramolecular C—H⋯O hydrogen bond, which generates an S(5) ring. The aromatic ring of the 4-chloro-3-nitrobenzoate ligand makes dihedral angles of 75.64 (12), 64.37 (12) and 2.97 (12)° with the three phenyl ligands. The O atoms of the nitro group are disordered over two sets of sites in a 0.817 (5):0.183 (5) ratio. In the crystal, molecules are linked via intermolecular C—H⋯O hydrogen bonds into chains running parallel to [010]. |
| format | Online Article Text |
| id | pubmed-3200665 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32006652011-11-06 (4-Chloro-3-nitrobenzoato)triphenyltin(IV) Win, Yip-Foo Choong, Chen-Shang Teoh, Siang-Guan Quah, Ching Kheng Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Sn(C(6)H(5))(3)(C(7)H(3)ClNO(4))], the four-coordinate Sn(IV) atom exists in a distorted tetrahedral geometry, formed by a monodentate carboxylate group and three phenyl rings. The conformation is stabilized by an intramolecular C—H⋯O hydrogen bond, which generates an S(5) ring. The aromatic ring of the 4-chloro-3-nitrobenzoate ligand makes dihedral angles of 75.64 (12), 64.37 (12) and 2.97 (12)° with the three phenyl ligands. The O atoms of the nitro group are disordered over two sets of sites in a 0.817 (5):0.183 (5) ratio. In the crystal, molecules are linked via intermolecular C—H⋯O hydrogen bonds into chains running parallel to [010]. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200665/ /pubmed/22065496 http://dx.doi.org/10.1107/S160053681103282X Text en © Win et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Win, Yip-Foo Choong, Chen-Shang Teoh, Siang-Guan Quah, Ching Kheng Fun, Hoong-Kun (4-Chloro-3-nitrobenzoato)triphenyltin(IV) |
| title | (4-Chloro-3-nitrobenzoato)triphenyltin(IV) |
| title_full | (4-Chloro-3-nitrobenzoato)triphenyltin(IV) |
| title_fullStr | (4-Chloro-3-nitrobenzoato)triphenyltin(IV) |
| title_full_unstemmed | (4-Chloro-3-nitrobenzoato)triphenyltin(IV) |
| title_short | (4-Chloro-3-nitrobenzoato)triphenyltin(IV) |
| title_sort | (4-chloro-3-nitrobenzoato)triphenyltin(iv) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200665/ https://www.ncbi.nlm.nih.gov/pubmed/22065496 http://dx.doi.org/10.1107/S160053681103282X |
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