catena-Poly[[diaqua­copper(II)]-μ-hy­drox­ido-κ(2) O:O-μ-[4-(4H-1,2,4-triazol-4-yl)benzoato]-κ(2) N (1):N (2)]

The title compound, [Cu(C(9)H(6)N(3)O(2))(OH)(H(2)O)(2)](n), adopts a chain motif along [010] in which the Cu(II) atoms are bridged by hy­droxy groups and 4-(1,2,4-triazol-4-yl)benzoate (tab) ligands. The Cu(II) atom lies on an inversion center and is six-coordinated by two N atoms from two tab liga...

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Detalles Bibliográficos
Autores principales: Shi, Haochen, Gao, Feng, Qi, Jingang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200671/
https://www.ncbi.nlm.nih.gov/pubmed/22058866
http://dx.doi.org/10.1107/S1600536811032624
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author Shi, Haochen
Gao, Feng
Qi, Jingang
author_facet Shi, Haochen
Gao, Feng
Qi, Jingang
author_sort Shi, Haochen
collection PubMed
description The title compound, [Cu(C(9)H(6)N(3)O(2))(OH)(H(2)O)(2)](n), adopts a chain motif along [010] in which the Cu(II) atoms are bridged by hy­droxy groups and 4-(1,2,4-triazol-4-yl)benzoate (tab) ligands. The Cu(II) atom lies on an inversion center and is six-coordinated by two N atoms from two tab ligands, two hy­droxy groups and two water mol­ecules, giving a distorted octa­hedral geometry. The hy­droxy group and the tab ligand are located on a mirror plane. One of the water H atoms is disordered over two positions with equal occupancy factors. Inter­molecular O—H⋯O hydrogen bonds extend the chains into a layer parallel to (100) and C—H⋯O hydrogen bonds connect the layers into a three-dimensional network.
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spelling pubmed-32006712011-11-06 catena-Poly[[diaqua­copper(II)]-μ-hy­drox­ido-κ(2) O:O-μ-[4-(4H-1,2,4-triazol-4-yl)benzoato]-κ(2) N (1):N (2)] Shi, Haochen Gao, Feng Qi, Jingang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(C(9)H(6)N(3)O(2))(OH)(H(2)O)(2)](n), adopts a chain motif along [010] in which the Cu(II) atoms are bridged by hy­droxy groups and 4-(1,2,4-triazol-4-yl)benzoate (tab) ligands. The Cu(II) atom lies on an inversion center and is six-coordinated by two N atoms from two tab ligands, two hy­droxy groups and two water mol­ecules, giving a distorted octa­hedral geometry. The hy­droxy group and the tab ligand are located on a mirror plane. One of the water H atoms is disordered over two positions with equal occupancy factors. Inter­molecular O—H⋯O hydrogen bonds extend the chains into a layer parallel to (100) and C—H⋯O hydrogen bonds connect the layers into a three-dimensional network. International Union of Crystallography 2011-08-17 /pmc/articles/PMC3200671/ /pubmed/22058866 http://dx.doi.org/10.1107/S1600536811032624 Text en © Shi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shi, Haochen
Gao, Feng
Qi, Jingang
catena-Poly[[diaqua­copper(II)]-μ-hy­drox­ido-κ(2) O:O-μ-[4-(4H-1,2,4-triazol-4-yl)benzoato]-κ(2) N (1):N (2)]
title catena-Poly[[diaqua­copper(II)]-μ-hy­drox­ido-κ(2) O:O-μ-[4-(4H-1,2,4-triazol-4-yl)benzoato]-κ(2) N (1):N (2)]
title_full catena-Poly[[diaqua­copper(II)]-μ-hy­drox­ido-κ(2) O:O-μ-[4-(4H-1,2,4-triazol-4-yl)benzoato]-κ(2) N (1):N (2)]
title_fullStr catena-Poly[[diaqua­copper(II)]-μ-hy­drox­ido-κ(2) O:O-μ-[4-(4H-1,2,4-triazol-4-yl)benzoato]-κ(2) N (1):N (2)]
title_full_unstemmed catena-Poly[[diaqua­copper(II)]-μ-hy­drox­ido-κ(2) O:O-μ-[4-(4H-1,2,4-triazol-4-yl)benzoato]-κ(2) N (1):N (2)]
title_short catena-Poly[[diaqua­copper(II)]-μ-hy­drox­ido-κ(2) O:O-μ-[4-(4H-1,2,4-triazol-4-yl)benzoato]-κ(2) N (1):N (2)]
title_sort catena-poly[[diaqua­copper(ii)]-μ-hy­drox­ido-κ(2) o:o-μ-[4-(4h-1,2,4-triazol-4-yl)benzoato]-κ(2) n (1):n (2)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200671/
https://www.ncbi.nlm.nih.gov/pubmed/22058866
http://dx.doi.org/10.1107/S1600536811032624
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AT qijingang catenapolydiaquacopperiimhydroxidok2oom44h124triazol4ylbenzoatok2n1n2

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