Chlorido(10,11,12,13-tetra­hydro-4,5,9,14-tetra­aza­benzo[b]triphenyl­ene-κ(2) N (4),N (5))copper(I)

The Cu(I) atom in the title compound, [CuCl(C(18)H(14)N(4))], is N,N′-chelated by the N-heterocyclic ligand and coordinated by one Cl(−) anion in a distorted trigonal geometry. In the crystal, the Cu(I) atom is disordered over two positions in a 0.667 (6):0.333 (6) ratio. The deviation of the Cu ato...

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Detalles Bibliográficos
Autores principales: Hong, Jun, Li, Xiu-Ying, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200675/
https://www.ncbi.nlm.nih.gov/pubmed/22065705
http://dx.doi.org/10.1107/S1600536811034817
Descripción
Sumario:The Cu(I) atom in the title compound, [CuCl(C(18)H(14)N(4))], is N,N′-chelated by the N-heterocyclic ligand and coordinated by one Cl(−) anion in a distorted trigonal geometry. In the crystal, the Cu(I) atom is disordered over two positions in a 0.667 (6):0.333 (6) ratio. The deviation of the Cu atom from the N/N/Cl coordination plane is 0.013 (3) Å for the major component and 0.073 (6) Å for the minor component. Two methyl­ene C atoms are also disordered over two positions in a 0.667 (6):0.333 (6) ratio.

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