Chlorido(10,11,12,13-tetra­hydro-4,5,9,14-tetra­aza­benzo[b]triphenyl­ene-κ(2) N (4),N (5))copper(I)

The Cu(I) atom in the title compound, [CuCl(C(18)H(14)N(4))], is N,N′-chelated by the N-heterocyclic ligand and coordinated by one Cl(−) anion in a distorted trigonal geometry. In the crystal, the Cu(I) atom is disordered over two positions in a 0.667 (6):0.333 (6) ratio. The deviation of the Cu ato...

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Detalles Bibliográficos
Autores principales: Hong, Jun, Li, Xiu-Ying, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200675/
https://www.ncbi.nlm.nih.gov/pubmed/22065705
http://dx.doi.org/10.1107/S1600536811034817
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author Hong, Jun
Li, Xiu-Ying
Ng, Seik Weng
author_facet Hong, Jun
Li, Xiu-Ying
Ng, Seik Weng
author_sort Hong, Jun
collection PubMed
description The Cu(I) atom in the title compound, [CuCl(C(18)H(14)N(4))], is N,N′-chelated by the N-heterocyclic ligand and coordinated by one Cl(−) anion in a distorted trigonal geometry. In the crystal, the Cu(I) atom is disordered over two positions in a 0.667 (6):0.333 (6) ratio. The deviation of the Cu atom from the N/N/Cl coordination plane is 0.013 (3) Å for the major component and 0.073 (6) Å for the minor component. Two methyl­ene C atoms are also disordered over two positions in a 0.667 (6):0.333 (6) ratio.
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spelling pubmed-32006752011-11-06 Chlorido(10,11,12,13-tetra­hydro-4,5,9,14-tetra­aza­benzo[b]triphenyl­ene-κ(2) N (4),N (5))copper(I) Hong, Jun Li, Xiu-Ying Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cu(I) atom in the title compound, [CuCl(C(18)H(14)N(4))], is N,N′-chelated by the N-heterocyclic ligand and coordinated by one Cl(−) anion in a distorted trigonal geometry. In the crystal, the Cu(I) atom is disordered over two positions in a 0.667 (6):0.333 (6) ratio. The deviation of the Cu atom from the N/N/Cl coordination plane is 0.013 (3) Å for the major component and 0.073 (6) Å for the minor component. Two methyl­ene C atoms are also disordered over two positions in a 0.667 (6):0.333 (6) ratio. International Union of Crystallography 2011-08-31 /pmc/articles/PMC3200675/ /pubmed/22065705 http://dx.doi.org/10.1107/S1600536811034817 Text en © Hong et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hong, Jun
Li, Xiu-Ying
Ng, Seik Weng
Chlorido(10,11,12,13-tetra­hydro-4,5,9,14-tetra­aza­benzo[b]triphenyl­ene-κ(2) N (4),N (5))copper(I)
title Chlorido(10,11,12,13-tetra­hydro-4,5,9,14-tetra­aza­benzo[b]triphenyl­ene-κ(2) N (4),N (5))copper(I)
title_full Chlorido(10,11,12,13-tetra­hydro-4,5,9,14-tetra­aza­benzo[b]triphenyl­ene-κ(2) N (4),N (5))copper(I)
title_fullStr Chlorido(10,11,12,13-tetra­hydro-4,5,9,14-tetra­aza­benzo[b]triphenyl­ene-κ(2) N (4),N (5))copper(I)
title_full_unstemmed Chlorido(10,11,12,13-tetra­hydro-4,5,9,14-tetra­aza­benzo[b]triphenyl­ene-κ(2) N (4),N (5))copper(I)
title_short Chlorido(10,11,12,13-tetra­hydro-4,5,9,14-tetra­aza­benzo[b]triphenyl­ene-κ(2) N (4),N (5))copper(I)
title_sort chlorido(10,11,12,13-tetra­hydro-4,5,9,14-tetra­aza­benzo[b]triphenyl­ene-κ(2) n (4),n (5))copper(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200675/
https://www.ncbi.nlm.nih.gov/pubmed/22065705
http://dx.doi.org/10.1107/S1600536811034817
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AT ngseikweng chlorido10111213tetrahydro45914tetraazabenzobtriphenylenek2n4n5copperi

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