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Poly[μ-aqua-diaqua(μ(3)-1H-benzimidazole-5-carboxylato-κ(3) N (3):O,O′)(μ(2)-1H-benzimidazole-5-carboxylato-κ(3) N (3):O:O′)-μ(5)-sulfato-μ(4)-sulfato-tricadmium]
The asymmetric unit of the title compound, [Cd(3)(C(8)H(5)N(2)O(2))(2)(SO(4))(2)(H(2)O)(3)](n), contains three Cd(II) ions, two sulfate anions, two 1H-benzimidazole-5-carboxylate (H(2)bic) ligands and three coordinated water molecules. One Cd(II) ion is six-coordinated and exhibits a distorted oct...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200680/ https://www.ncbi.nlm.nih.gov/pubmed/22058893 http://dx.doi.org/10.1107/S1600536811034477 |
Sumario: | The asymmetric unit of the title compound, [Cd(3)(C(8)H(5)N(2)O(2))(2)(SO(4))(2)(H(2)O)(3)](n), contains three Cd(II) ions, two sulfate anions, two 1H-benzimidazole-5-carboxylate (H(2)bic) ligands and three coordinated water molecules. One Cd(II) ion is six-coordinated and exhibits a distorted octahedral geometry, while the other two Cd(II) ions are seven-coordinated, displaying a distorted pentagonal–bipyramidal geometry. The Cd(II) ions are bridged by two types of sulfate anions, producing inorganic chains along [100]. These chains are further connected by the H(2)bic ligands, leading to a three-dimensional framework. N—H⋯O and O—H⋯O hydrogen bonds and π–π interactions between the imidazole and benzene rings [centroid–centroid distances = 3.953 (2), 3.507 (2), 3.407 (2) and 3.561 (2) Å] further stabilize the crystal structure. |
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