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Poly[diaqua(μ-4,4′-bipyridine-κ(2) N:N′)[μ-2,2′-(p-phenylenedioxy)diacetato-κ(2) O:O′]cadmium]
In the title compound, [Cd(C(10)H(8)O(6))(C(10)H(8)N(2))(H(2)O)(2)](n), the Cd(II) ion has inversion symmetry and is coordinated by O atoms from two water molecules and two bridging 2,2′-(μ-p-phenylenedioxy)diacetate ligands and two N atoms from two 4,4′-bipyridine ligands, giving a slightly dist...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200682/ https://www.ncbi.nlm.nih.gov/pubmed/22058862 http://dx.doi.org/10.1107/S1600536811031400 |
Sumario: | In the title compound, [Cd(C(10)H(8)O(6))(C(10)H(8)N(2))(H(2)O)(2)](n), the Cd(II) ion has inversion symmetry and is coordinated by O atoms from two water molecules and two bridging 2,2′-(μ-p-phenylenedioxy)diacetate ligands and two N atoms from two 4,4′-bipyridine ligands, giving a slightly distorted octahedral geometry. The diacetate and 4,4′-bipyridine ligands also lie across inversion centers. The bridging ligands form layers parallel to (11[Image: see text]), with adjacent layers interconnected via O—H⋯O hydrogen bonds between the coordinated water molecules and the carboxylate O atoms, giving a three-dimensional supramolecular architecture. |
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