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Poly[diaqua(μ-4,4′-bipyridine-κ(2) N:N′)[μ-2,2′-(p-phenylenedioxy)diacetato-κ(2) O:O′]cadmium]
In the title compound, [Cd(C(10)H(8)O(6))(C(10)H(8)N(2))(H(2)O)(2)](n), the Cd(II) ion has inversion symmetry and is coordinated by O atoms from two water molecules and two bridging 2,2′-(μ-p-phenylenedioxy)diacetate ligands and two N atoms from two 4,4′-bipyridine ligands, giving a slightly dist...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200682/ https://www.ncbi.nlm.nih.gov/pubmed/22058862 http://dx.doi.org/10.1107/S1600536811031400 |
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author | Wang, Guang-Yin |
author_facet | Wang, Guang-Yin |
author_sort | Wang, Guang-Yin |
collection | PubMed |
description | In the title compound, [Cd(C(10)H(8)O(6))(C(10)H(8)N(2))(H(2)O)(2)](n), the Cd(II) ion has inversion symmetry and is coordinated by O atoms from two water molecules and two bridging 2,2′-(μ-p-phenylenedioxy)diacetate ligands and two N atoms from two 4,4′-bipyridine ligands, giving a slightly distorted octahedral geometry. The diacetate and 4,4′-bipyridine ligands also lie across inversion centers. The bridging ligands form layers parallel to (11[Image: see text]), with adjacent layers interconnected via O—H⋯O hydrogen bonds between the coordinated water molecules and the carboxylate O atoms, giving a three-dimensional supramolecular architecture. |
format | Online Article Text |
id | pubmed-3200682 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32006822011-11-06 Poly[diaqua(μ-4,4′-bipyridine-κ(2) N:N′)[μ-2,2′-(p-phenylenedioxy)diacetato-κ(2) O:O′]cadmium] Wang, Guang-Yin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(10)H(8)O(6))(C(10)H(8)N(2))(H(2)O)(2)](n), the Cd(II) ion has inversion symmetry and is coordinated by O atoms from two water molecules and two bridging 2,2′-(μ-p-phenylenedioxy)diacetate ligands and two N atoms from two 4,4′-bipyridine ligands, giving a slightly distorted octahedral geometry. The diacetate and 4,4′-bipyridine ligands also lie across inversion centers. The bridging ligands form layers parallel to (11[Image: see text]), with adjacent layers interconnected via O—H⋯O hydrogen bonds between the coordinated water molecules and the carboxylate O atoms, giving a three-dimensional supramolecular architecture. International Union of Crystallography 2011-08-17 /pmc/articles/PMC3200682/ /pubmed/22058862 http://dx.doi.org/10.1107/S1600536811031400 Text en © Guang-Yin Wang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Guang-Yin Poly[diaqua(μ-4,4′-bipyridine-κ(2) N:N′)[μ-2,2′-(p-phenylenedioxy)diacetato-κ(2) O:O′]cadmium] |
title | Poly[diaqua(μ-4,4′-bipyridine-κ(2)
N:N′)[μ-2,2′-(p-phenylenedioxy)diacetato-κ(2)
O:O′]cadmium] |
title_full | Poly[diaqua(μ-4,4′-bipyridine-κ(2)
N:N′)[μ-2,2′-(p-phenylenedioxy)diacetato-κ(2)
O:O′]cadmium] |
title_fullStr | Poly[diaqua(μ-4,4′-bipyridine-κ(2)
N:N′)[μ-2,2′-(p-phenylenedioxy)diacetato-κ(2)
O:O′]cadmium] |
title_full_unstemmed | Poly[diaqua(μ-4,4′-bipyridine-κ(2)
N:N′)[μ-2,2′-(p-phenylenedioxy)diacetato-κ(2)
O:O′]cadmium] |
title_short | Poly[diaqua(μ-4,4′-bipyridine-κ(2)
N:N′)[μ-2,2′-(p-phenylenedioxy)diacetato-κ(2)
O:O′]cadmium] |
title_sort | poly[diaqua(μ-4,4′-bipyridine-κ(2)
n:n′)[μ-2,2′-(p-phenylenedioxy)diacetato-κ(2)
o:o′]cadmium] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200682/ https://www.ncbi.nlm.nih.gov/pubmed/22058862 http://dx.doi.org/10.1107/S1600536811031400 |
work_keys_str_mv | AT wangguangyin polydiaquam44bipyridinek2nnm22pphenylenedioxydiacetatok2oocadmium |