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Poly[diaqua­(μ-4,4′-bipyridine-κ(2) N:N′)[μ-2,2′-(p-phenyl­enedi­oxy)diacetato-κ(2) O:O′]cadmium]

In the title compound, [Cd(C(10)H(8)O(6))(C(10)H(8)N(2))(H(2)O)(2)](n), the Cd(II) ion has inversion symmetry and is coordinated by O atoms from two water mol­ecules and two bridging 2,2′-(μ-p-phenyl­enedi­oxy)diacetate ligands and two N atoms from two 4,4′-bipyridine ligands, giving a slightly dist...

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Detalles Bibliográficos
Autor principal: Wang, Guang-Yin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200682/
https://www.ncbi.nlm.nih.gov/pubmed/22058862
http://dx.doi.org/10.1107/S1600536811031400
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author Wang, Guang-Yin
author_facet Wang, Guang-Yin
author_sort Wang, Guang-Yin
collection PubMed
description In the title compound, [Cd(C(10)H(8)O(6))(C(10)H(8)N(2))(H(2)O)(2)](n), the Cd(II) ion has inversion symmetry and is coordinated by O atoms from two water mol­ecules and two bridging 2,2′-(μ-p-phenyl­enedi­oxy)diacetate ligands and two N atoms from two 4,4′-bipyridine ligands, giving a slightly distorted octa­hedral geometry. The diacetate and 4,4′-bipyridine ligands also lie across inversion centers. The bridging ligands form layers parallel to (11[Image: see text]), with adjacent layers inter­connected via O—H⋯O hydrogen bonds between the coordinated water mol­ecules and the carboxyl­ate O atoms, giving a three-dimensional supra­molecular architecture.
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spelling pubmed-32006822011-11-06 Poly[diaqua­(μ-4,4′-bipyridine-κ(2) N:N′)[μ-2,2′-(p-phenyl­enedi­oxy)diacetato-κ(2) O:O′]cadmium] Wang, Guang-Yin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(10)H(8)O(6))(C(10)H(8)N(2))(H(2)O)(2)](n), the Cd(II) ion has inversion symmetry and is coordinated by O atoms from two water mol­ecules and two bridging 2,2′-(μ-p-phenyl­enedi­oxy)diacetate ligands and two N atoms from two 4,4′-bipyridine ligands, giving a slightly distorted octa­hedral geometry. The diacetate and 4,4′-bipyridine ligands also lie across inversion centers. The bridging ligands form layers parallel to (11[Image: see text]), with adjacent layers inter­connected via O—H⋯O hydrogen bonds between the coordinated water mol­ecules and the carboxyl­ate O atoms, giving a three-dimensional supra­molecular architecture. International Union of Crystallography 2011-08-17 /pmc/articles/PMC3200682/ /pubmed/22058862 http://dx.doi.org/10.1107/S1600536811031400 Text en © Guang-Yin Wang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Guang-Yin
Poly[diaqua­(μ-4,4′-bipyridine-κ(2) N:N′)[μ-2,2′-(p-phenyl­enedi­oxy)diacetato-κ(2) O:O′]cadmium]
title Poly[diaqua­(μ-4,4′-bipyridine-κ(2) N:N′)[μ-2,2′-(p-phenyl­enedi­oxy)diacetato-κ(2) O:O′]cadmium]
title_full Poly[diaqua­(μ-4,4′-bipyridine-κ(2) N:N′)[μ-2,2′-(p-phenyl­enedi­oxy)diacetato-κ(2) O:O′]cadmium]
title_fullStr Poly[diaqua­(μ-4,4′-bipyridine-κ(2) N:N′)[μ-2,2′-(p-phenyl­enedi­oxy)diacetato-κ(2) O:O′]cadmium]
title_full_unstemmed Poly[diaqua­(μ-4,4′-bipyridine-κ(2) N:N′)[μ-2,2′-(p-phenyl­enedi­oxy)diacetato-κ(2) O:O′]cadmium]
title_short Poly[diaqua­(μ-4,4′-bipyridine-κ(2) N:N′)[μ-2,2′-(p-phenyl­enedi­oxy)diacetato-κ(2) O:O′]cadmium]
title_sort poly[diaqua­(μ-4,4′-bipyridine-κ(2) n:n′)[μ-2,2′-(p-phenyl­enedi­oxy)diacetato-κ(2) o:o′]cadmium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200682/
https://www.ncbi.nlm.nih.gov/pubmed/22058862
http://dx.doi.org/10.1107/S1600536811031400
work_keys_str_mv AT wangguangyin polydiaquam44bipyridinek2nnm22pphenylenedioxydiacetatok2oocadmium