(S)-(−)-1-Phenyl­ethanaminium 4-(4,4-di­fluoro-1,3,5,7-tetra­methyl-3a,4a-diaza-4-borata-s-indacen-8-yl)benzoate

The title compound, C(8)H(12)N(+)·C(20)H(18)BF(2)N(2)O(2) (−), crystallizes with a significant amount of void space [4.0 (5)%] in the unit cell. The structure displays N—H⋯O hydrogen bonding between the components. The plane formed by the benzoic acid moiety of the BODIPY-CO(2) (−) is twisted by 80....

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Detalles Bibliográficos
Autores principales: Hinkle, Lindsay M., Chitta, Raghu, Mann, Kent R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200683/
https://www.ncbi.nlm.nih.gov/pubmed/22058921
http://dx.doi.org/10.1107/S1600536811019167
Descripción
Sumario:The title compound, C(8)H(12)N(+)·C(20)H(18)BF(2)N(2)O(2) (−), crystallizes with a significant amount of void space [4.0 (5)%] in the unit cell. The structure displays N—H⋯O hydrogen bonding between the components. The plane formed by the benzoic acid moiety of the BODIPY-CO(2) (−) is twisted by 80.71 (6)° relative to the plane formed by the ring C and N atoms of the tetramethyldipyrrin portion of the molecule.

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