(S)-(−)-1-Phenyl­ethanaminium 4-(4,4-di­fluoro-1,3,5,7-tetra­methyl-3a,4a-diaza-4-borata-s-indacen-8-yl)benzoate

The title compound, C(8)H(12)N(+)·C(20)H(18)BF(2)N(2)O(2) (−), crystallizes with a significant amount of void space [4.0 (5)%] in the unit cell. The structure displays N—H⋯O hydrogen bonding between the components. The plane formed by the benzoic acid moiety of the BODIPY-CO(2) (−) is twisted by 80....

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Detalles Bibliográficos
Autores principales: Hinkle, Lindsay M., Chitta, Raghu, Mann, Kent R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200683/
https://www.ncbi.nlm.nih.gov/pubmed/22058921
http://dx.doi.org/10.1107/S1600536811019167
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author Hinkle, Lindsay M.
Chitta, Raghu
Mann, Kent R.
author_facet Hinkle, Lindsay M.
Chitta, Raghu
Mann, Kent R.
author_sort Hinkle, Lindsay M.
collection PubMed
description The title compound, C(8)H(12)N(+)·C(20)H(18)BF(2)N(2)O(2) (−), crystallizes with a significant amount of void space [4.0 (5)%] in the unit cell. The structure displays N—H⋯O hydrogen bonding between the components. The plane formed by the benzoic acid moiety of the BODIPY-CO(2) (−) is twisted by 80.71 (6)° relative to the plane formed by the ring C and N atoms of the tetramethyldipyrrin portion of the molecule.
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spelling pubmed-32006832011-11-06 (S)-(−)-1-Phenyl­ethanaminium 4-(4,4-di­fluoro-1,3,5,7-tetra­methyl-3a,4a-diaza-4-borata-s-indacen-8-yl)benzoate Hinkle, Lindsay M. Chitta, Raghu Mann, Kent R. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(8)H(12)N(+)·C(20)H(18)BF(2)N(2)O(2) (−), crystallizes with a significant amount of void space [4.0 (5)%] in the unit cell. The structure displays N—H⋯O hydrogen bonding between the components. The plane formed by the benzoic acid moiety of the BODIPY-CO(2) (−) is twisted by 80.71 (6)° relative to the plane formed by the ring C and N atoms of the tetramethyldipyrrin portion of the molecule. International Union of Crystallography 2011-08-06 /pmc/articles/PMC3200683/ /pubmed/22058921 http://dx.doi.org/10.1107/S1600536811019167 Text en © Hinkle et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hinkle, Lindsay M.
Chitta, Raghu
Mann, Kent R.
(S)-(−)-1-Phenyl­ethanaminium 4-(4,4-di­fluoro-1,3,5,7-tetra­methyl-3a,4a-diaza-4-borata-s-indacen-8-yl)benzoate
title (S)-(−)-1-Phenyl­ethanaminium 4-(4,4-di­fluoro-1,3,5,7-tetra­methyl-3a,4a-diaza-4-borata-s-indacen-8-yl)benzoate
title_full (S)-(−)-1-Phenyl­ethanaminium 4-(4,4-di­fluoro-1,3,5,7-tetra­methyl-3a,4a-diaza-4-borata-s-indacen-8-yl)benzoate
title_fullStr (S)-(−)-1-Phenyl­ethanaminium 4-(4,4-di­fluoro-1,3,5,7-tetra­methyl-3a,4a-diaza-4-borata-s-indacen-8-yl)benzoate
title_full_unstemmed (S)-(−)-1-Phenyl­ethanaminium 4-(4,4-di­fluoro-1,3,5,7-tetra­methyl-3a,4a-diaza-4-borata-s-indacen-8-yl)benzoate
title_short (S)-(−)-1-Phenyl­ethanaminium 4-(4,4-di­fluoro-1,3,5,7-tetra­methyl-3a,4a-diaza-4-borata-s-indacen-8-yl)benzoate
title_sort (s)-(−)-1-phenyl­ethanaminium 4-(4,4-di­fluoro-1,3,5,7-tetra­methyl-3a,4a-diaza-4-borata-s-indacen-8-yl)benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200683/
https://www.ncbi.nlm.nih.gov/pubmed/22058921
http://dx.doi.org/10.1107/S1600536811019167
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AT mannkentr s1phenylethanaminium444difluoro1357tetramethyl3a4adiaza4boratasindacen8ylbenzoate

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