Chlorido(8-hy­droxy­quinoline-κ(2) N,O)(quinolin-8-olato-κ(2) N,O)zinc methanol monosolvate

In the title compound, [Zn(C(9)H(6)NO)Cl(C(9)H(7)NO)]·CH(3)OH, the Zn(II) ion is N,O-chelated by both a neutral and a deprotonated quinolin-8-ol ligand, with a chloride ligand in the apical site completing the square-pyramidal coordination geometry. The Zn(II) ion is displaced by 0.586 Å in the dire...

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Detalles Bibliográficos
Autores principales: Najafi, Ezzatollah, Amini, Mostafa M., Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200687/
https://www.ncbi.nlm.nih.gov/pubmed/22058878
http://dx.doi.org/10.1107/S160053681103337X
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author Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_facet Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_sort Najafi, Ezzatollah
collection PubMed
description In the title compound, [Zn(C(9)H(6)NO)Cl(C(9)H(7)NO)]·CH(3)OH, the Zn(II) ion is N,O-chelated by both a neutral and a deprotonated quinolin-8-ol ligand, with a chloride ligand in the apical site completing the square-pyramidal coordination geometry. The Zn(II) ion is displaced by 0.586 Å in the direction of the chloride ligand from the atoms forming the square plane. In the crystal, the components are linked by inter­molecular O—H⋯O hydrogen bonds, generating chains along the b axis.
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spelling pubmed-32006872011-11-06 Chlorido(8-hy­droxy­quinoline-κ(2) N,O)(quinolin-8-olato-κ(2) N,O)zinc methanol monosolvate Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(9)H(6)NO)Cl(C(9)H(7)NO)]·CH(3)OH, the Zn(II) ion is N,O-chelated by both a neutral and a deprotonated quinolin-8-ol ligand, with a chloride ligand in the apical site completing the square-pyramidal coordination geometry. The Zn(II) ion is displaced by 0.586 Å in the direction of the chloride ligand from the atoms forming the square plane. In the crystal, the components are linked by inter­molecular O—H⋯O hydrogen bonds, generating chains along the b axis. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200687/ /pubmed/22058878 http://dx.doi.org/10.1107/S160053681103337X Text en © Najafi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
Chlorido(8-hy­droxy­quinoline-κ(2) N,O)(quinolin-8-olato-κ(2) N,O)zinc methanol monosolvate
title Chlorido(8-hy­droxy­quinoline-κ(2) N,O)(quinolin-8-olato-κ(2) N,O)zinc methanol monosolvate
title_full Chlorido(8-hy­droxy­quinoline-κ(2) N,O)(quinolin-8-olato-κ(2) N,O)zinc methanol monosolvate
title_fullStr Chlorido(8-hy­droxy­quinoline-κ(2) N,O)(quinolin-8-olato-κ(2) N,O)zinc methanol monosolvate
title_full_unstemmed Chlorido(8-hy­droxy­quinoline-κ(2) N,O)(quinolin-8-olato-κ(2) N,O)zinc methanol monosolvate
title_short Chlorido(8-hy­droxy­quinoline-κ(2) N,O)(quinolin-8-olato-κ(2) N,O)zinc methanol monosolvate
title_sort chlorido(8-hy­droxy­quinoline-κ(2) n,o)(quinolin-8-olato-κ(2) n,o)zinc methanol monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200687/
https://www.ncbi.nlm.nih.gov/pubmed/22058878
http://dx.doi.org/10.1107/S160053681103337X
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