Cargando…
(1E,1′E)-4,4′-[1,1′-(Hydrazine-1,2-diylidene)bis(ethan-1-yl-1-ylidene)]diphenol dihydrate
The asymmetric unit of the title compound, C(16)H(16)N(2)O(2)·2H(2)O, contains one half-molecule of diphenol and one water molecule. The complete diphenol molecule is generated by a crystallographic inversion centre. In the molecule, the central C(methyl)—C=N—N=C—C(methyl) plane makes a dihedr...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200688/ https://www.ncbi.nlm.nih.gov/pubmed/22064463 http://dx.doi.org/10.1107/S1600536811029679 |
_version_ | 1782214726958186496 |
---|---|
author | Chantrapromma, Suchada Jansrisewangwong, Patcharaporn Chanawanno, Kullapa Fun, Hoong-Kun |
author_facet | Chantrapromma, Suchada Jansrisewangwong, Patcharaporn Chanawanno, Kullapa Fun, Hoong-Kun |
author_sort | Chantrapromma, Suchada |
collection | PubMed |
description | The asymmetric unit of the title compound, C(16)H(16)N(2)O(2)·2H(2)O, contains one half-molecule of diphenol and one water molecule. The complete diphenol molecule is generated by a crystallographic inversion centre. In the molecule, the central C(methyl)—C=N—N=C—C(methyl) plane makes a dihedral angle of 8.88 (6)° with its adjacent benzene ring. In the crystal, the components are linked by O—H⋯N and O—H⋯O hydrogen bonds into a three-dimensional network. The crystal structure is further stabilized by a weak C—H⋯π interaction. |
format | Online Article Text |
id | pubmed-3200688 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32006882011-11-06 (1E,1′E)-4,4′-[1,1′-(Hydrazine-1,2-diylidene)bis(ethan-1-yl-1-ylidene)]diphenol dihydrate Chantrapromma, Suchada Jansrisewangwong, Patcharaporn Chanawanno, Kullapa Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(16)H(16)N(2)O(2)·2H(2)O, contains one half-molecule of diphenol and one water molecule. The complete diphenol molecule is generated by a crystallographic inversion centre. In the molecule, the central C(methyl)—C=N—N=C—C(methyl) plane makes a dihedral angle of 8.88 (6)° with its adjacent benzene ring. In the crystal, the components are linked by O—H⋯N and O—H⋯O hydrogen bonds into a three-dimensional network. The crystal structure is further stabilized by a weak C—H⋯π interaction. International Union of Crystallography 2011-08-02 /pmc/articles/PMC3200688/ /pubmed/22064463 http://dx.doi.org/10.1107/S1600536811029679 Text en © Chantrapromma et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Chantrapromma, Suchada Jansrisewangwong, Patcharaporn Chanawanno, Kullapa Fun, Hoong-Kun (1E,1′E)-4,4′-[1,1′-(Hydrazine-1,2-diylidene)bis(ethan-1-yl-1-ylidene)]diphenol dihydrate |
title | (1E,1′E)-4,4′-[1,1′-(Hydrazine-1,2-diylidene)bis(ethan-1-yl-1-ylidene)]diphenol dihydrate |
title_full | (1E,1′E)-4,4′-[1,1′-(Hydrazine-1,2-diylidene)bis(ethan-1-yl-1-ylidene)]diphenol dihydrate |
title_fullStr | (1E,1′E)-4,4′-[1,1′-(Hydrazine-1,2-diylidene)bis(ethan-1-yl-1-ylidene)]diphenol dihydrate |
title_full_unstemmed | (1E,1′E)-4,4′-[1,1′-(Hydrazine-1,2-diylidene)bis(ethan-1-yl-1-ylidene)]diphenol dihydrate |
title_short | (1E,1′E)-4,4′-[1,1′-(Hydrazine-1,2-diylidene)bis(ethan-1-yl-1-ylidene)]diphenol dihydrate |
title_sort | (1e,1′e)-4,4′-[1,1′-(hydrazine-1,2-diylidene)bis(ethan-1-yl-1-ylidene)]diphenol dihydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200688/ https://www.ncbi.nlm.nih.gov/pubmed/22064463 http://dx.doi.org/10.1107/S1600536811029679 |
work_keys_str_mv | AT chantraprommasuchada 1e1e4411hydrazine12diylidenebisethan1yl1ylidenediphenoldihydrate AT jansrisewangwongpatcharaporn 1e1e4411hydrazine12diylidenebisethan1yl1ylidenediphenoldihydrate AT chanawannokullapa 1e1e4411hydrazine12diylidenebisethan1yl1ylidenediphenoldihydrate AT funhoongkun 1e1e4411hydrazine12diylidenebisethan1yl1ylidenediphenoldihydrate |