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catena-Poly[[bis[[bis(3-aminopropyl)amine-κ(3) N,N′,N′′](thiocyanato-κN)cadmium]-μ(4)-sulfato-κ(4) O,O:O′,O′] methanol hemisolvate]
The asymmetric unit of the title compound, {[Cd(2)(NCS)(2)(SO(4))(C(6)H(17)N(3))(2)]·0.5CH(3)OH}(n), consists of two Cd(2+) cations, two thiocyanate and one sulfate anion, two bis(3-aminopropyl)amine co-ligands and one methanol molecule with half-occupancy. Each Cd(2+) cation is coordinated by f...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200697/ https://www.ncbi.nlm.nih.gov/pubmed/22058845 http://dx.doi.org/10.1107/S1600536811031163 |
Sumario: | The asymmetric unit of the title compound, {[Cd(2)(NCS)(2)(SO(4))(C(6)H(17)N(3))(2)]·0.5CH(3)OH}(n), consists of two Cd(2+) cations, two thiocyanate and one sulfate anion, two bis(3-aminopropyl)amine co-ligands and one methanol molecule with half-occupancy. Each Cd(2+) cation is coordinated by four N atoms of one terminal N-bonded thiocyanate anion and one bis(3-aminopropyl)amine co-ligand, and by two O atoms of two symmetry-related sulfate anions, defining a slightly distorted octahedral coordination polyhedron. Each two Cd(2+) cations are connected into dimers, which are located on centres of inversion and which are further μ-1,1:3,3-bridged via the sulfate anions into polymeric zigzag chains along the a axis. |
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