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catena-Poly[[bis­[[bis­(3-amino­prop­yl)amine-κ(3) N,N′,N′′](thio­cyanato-κN)cadmium]-μ(4)-sulfato-κ(4) O,O:O′,O′] methanol hemisolvate]

The asymmetric unit of the title compound, {[Cd(2)(NCS)(2)(SO(4))(C(6)H(17)N(3))(2)]·0.5CH(3)OH}(n), consists of two Cd(2+) cations, two thio­cyanate and one sulfate anion, two bis­(3-amino­prop­yl)amine co-ligands and one methanol molecule with half-occupancy. Each Cd(2+) cation is coordinated by f...

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Detalles Bibliográficos
Autores principales: Boeckmann, Jan, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200697/
https://www.ncbi.nlm.nih.gov/pubmed/22058845
http://dx.doi.org/10.1107/S1600536811031163
Descripción
Sumario:The asymmetric unit of the title compound, {[Cd(2)(NCS)(2)(SO(4))(C(6)H(17)N(3))(2)]·0.5CH(3)OH}(n), consists of two Cd(2+) cations, two thio­cyanate and one sulfate anion, two bis­(3-amino­prop­yl)amine co-ligands and one methanol molecule with half-occupancy. Each Cd(2+) cation is coordinated by four N atoms of one terminal N-bonded thio­cyanate anion and one bis­(3-amino­prop­yl)amine co-ligand, and by two O atoms of two symmetry-related sulfate anions, defining a slightly distorted octa­hedral coordination polyhedron. Each two Cd(2+) cations are connected into dimers, which are located on centres of inversion and which are further μ-1,1:3,3-bridged via the sulfate anions into polymeric zigzag chains along the a axis.