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catena-Poly[[bis[[bis(3-aminopropyl)amine-κ(3) N,N′,N′′](thiocyanato-κN)cadmium]-μ(4)-sulfato-κ(4) O,O:O′,O′] methanol hemisolvate]
The asymmetric unit of the title compound, {[Cd(2)(NCS)(2)(SO(4))(C(6)H(17)N(3))(2)]·0.5CH(3)OH}(n), consists of two Cd(2+) cations, two thiocyanate and one sulfate anion, two bis(3-aminopropyl)amine co-ligands and one methanol molecule with half-occupancy. Each Cd(2+) cation is coordinated by f...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200697/ https://www.ncbi.nlm.nih.gov/pubmed/22058845 http://dx.doi.org/10.1107/S1600536811031163 |
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author | Boeckmann, Jan Näther, Christian |
author_facet | Boeckmann, Jan Näther, Christian |
author_sort | Boeckmann, Jan |
collection | PubMed |
description | The asymmetric unit of the title compound, {[Cd(2)(NCS)(2)(SO(4))(C(6)H(17)N(3))(2)]·0.5CH(3)OH}(n), consists of two Cd(2+) cations, two thiocyanate and one sulfate anion, two bis(3-aminopropyl)amine co-ligands and one methanol molecule with half-occupancy. Each Cd(2+) cation is coordinated by four N atoms of one terminal N-bonded thiocyanate anion and one bis(3-aminopropyl)amine co-ligand, and by two O atoms of two symmetry-related sulfate anions, defining a slightly distorted octahedral coordination polyhedron. Each two Cd(2+) cations are connected into dimers, which are located on centres of inversion and which are further μ-1,1:3,3-bridged via the sulfate anions into polymeric zigzag chains along the a axis. |
format | Online Article Text |
id | pubmed-3200697 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32006972011-11-06 catena-Poly[[bis[[bis(3-aminopropyl)amine-κ(3) N,N′,N′′](thiocyanato-κN)cadmium]-μ(4)-sulfato-κ(4) O,O:O′,O′] methanol hemisolvate] Boeckmann, Jan Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, {[Cd(2)(NCS)(2)(SO(4))(C(6)H(17)N(3))(2)]·0.5CH(3)OH}(n), consists of two Cd(2+) cations, two thiocyanate and one sulfate anion, two bis(3-aminopropyl)amine co-ligands and one methanol molecule with half-occupancy. Each Cd(2+) cation is coordinated by four N atoms of one terminal N-bonded thiocyanate anion and one bis(3-aminopropyl)amine co-ligand, and by two O atoms of two symmetry-related sulfate anions, defining a slightly distorted octahedral coordination polyhedron. Each two Cd(2+) cations are connected into dimers, which are located on centres of inversion and which are further μ-1,1:3,3-bridged via the sulfate anions into polymeric zigzag chains along the a axis. International Union of Crystallography 2011-08-06 /pmc/articles/PMC3200697/ /pubmed/22058845 http://dx.doi.org/10.1107/S1600536811031163 Text en © Boeckmann and Näther 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Boeckmann, Jan Näther, Christian catena-Poly[[bis[[bis(3-aminopropyl)amine-κ(3) N,N′,N′′](thiocyanato-κN)cadmium]-μ(4)-sulfato-κ(4) O,O:O′,O′] methanol hemisolvate] |
title |
catena-Poly[[bis[[bis(3-aminopropyl)amine-κ(3)
N,N′,N′′](thiocyanato-κN)cadmium]-μ(4)-sulfato-κ(4)
O,O:O′,O′] methanol hemisolvate] |
title_full |
catena-Poly[[bis[[bis(3-aminopropyl)amine-κ(3)
N,N′,N′′](thiocyanato-κN)cadmium]-μ(4)-sulfato-κ(4)
O,O:O′,O′] methanol hemisolvate] |
title_fullStr |
catena-Poly[[bis[[bis(3-aminopropyl)amine-κ(3)
N,N′,N′′](thiocyanato-κN)cadmium]-μ(4)-sulfato-κ(4)
O,O:O′,O′] methanol hemisolvate] |
title_full_unstemmed |
catena-Poly[[bis[[bis(3-aminopropyl)amine-κ(3)
N,N′,N′′](thiocyanato-κN)cadmium]-μ(4)-sulfato-κ(4)
O,O:O′,O′] methanol hemisolvate] |
title_short |
catena-Poly[[bis[[bis(3-aminopropyl)amine-κ(3)
N,N′,N′′](thiocyanato-κN)cadmium]-μ(4)-sulfato-κ(4)
O,O:O′,O′] methanol hemisolvate] |
title_sort | catena-poly[[bis[[bis(3-aminopropyl)amine-κ(3)
n,n′,n′′](thiocyanato-κn)cadmium]-μ(4)-sulfato-κ(4)
o,o:o′,o′] methanol hemisolvate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200697/ https://www.ncbi.nlm.nih.gov/pubmed/22058845 http://dx.doi.org/10.1107/S1600536811031163 |
work_keys_str_mv | AT boeckmannjan catenapolybisbis3aminopropylaminek3nnnthiocyanatokncadmiumm4sulfatok4oooomethanolhemisolvate AT natherchristian catenapolybisbis3aminopropylaminek3nnnthiocyanatokncadmiumm4sulfatok4oooomethanolhemisolvate |