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catena-Poly[[bis­[[bis­(3-amino­prop­yl)amine-κ(3) N,N′,N′′](thio­cyanato-κN)cadmium]-μ(4)-sulfato-κ(4) O,O:O′,O′] methanol hemisolvate]

The asymmetric unit of the title compound, {[Cd(2)(NCS)(2)(SO(4))(C(6)H(17)N(3))(2)]·0.5CH(3)OH}(n), consists of two Cd(2+) cations, two thio­cyanate and one sulfate anion, two bis­(3-amino­prop­yl)amine co-ligands and one methanol molecule with half-occupancy. Each Cd(2+) cation is coordinated by f...

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Detalles Bibliográficos
Autores principales: Boeckmann, Jan, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200697/
https://www.ncbi.nlm.nih.gov/pubmed/22058845
http://dx.doi.org/10.1107/S1600536811031163
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author Boeckmann, Jan
Näther, Christian
author_facet Boeckmann, Jan
Näther, Christian
author_sort Boeckmann, Jan
collection PubMed
description The asymmetric unit of the title compound, {[Cd(2)(NCS)(2)(SO(4))(C(6)H(17)N(3))(2)]·0.5CH(3)OH}(n), consists of two Cd(2+) cations, two thio­cyanate and one sulfate anion, two bis­(3-amino­prop­yl)amine co-ligands and one methanol molecule with half-occupancy. Each Cd(2+) cation is coordinated by four N atoms of one terminal N-bonded thio­cyanate anion and one bis­(3-amino­prop­yl)amine co-ligand, and by two O atoms of two symmetry-related sulfate anions, defining a slightly distorted octa­hedral coordination polyhedron. Each two Cd(2+) cations are connected into dimers, which are located on centres of inversion and which are further μ-1,1:3,3-bridged via the sulfate anions into polymeric zigzag chains along the a axis.
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spelling pubmed-32006972011-11-06 catena-Poly[[bis­[[bis­(3-amino­prop­yl)amine-κ(3) N,N′,N′′](thio­cyanato-κN)cadmium]-μ(4)-sulfato-κ(4) O,O:O′,O′] methanol hemisolvate] Boeckmann, Jan Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, {[Cd(2)(NCS)(2)(SO(4))(C(6)H(17)N(3))(2)]·0.5CH(3)OH}(n), consists of two Cd(2+) cations, two thio­cyanate and one sulfate anion, two bis­(3-amino­prop­yl)amine co-ligands and one methanol molecule with half-occupancy. Each Cd(2+) cation is coordinated by four N atoms of one terminal N-bonded thio­cyanate anion and one bis­(3-amino­prop­yl)amine co-ligand, and by two O atoms of two symmetry-related sulfate anions, defining a slightly distorted octa­hedral coordination polyhedron. Each two Cd(2+) cations are connected into dimers, which are located on centres of inversion and which are further μ-1,1:3,3-bridged via the sulfate anions into polymeric zigzag chains along the a axis. International Union of Crystallography 2011-08-06 /pmc/articles/PMC3200697/ /pubmed/22058845 http://dx.doi.org/10.1107/S1600536811031163 Text en © Boeckmann and Näther 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Boeckmann, Jan
Näther, Christian
catena-Poly[[bis­[[bis­(3-amino­prop­yl)amine-κ(3) N,N′,N′′](thio­cyanato-κN)cadmium]-μ(4)-sulfato-κ(4) O,O:O′,O′] methanol hemisolvate]
title catena-Poly[[bis­[[bis­(3-amino­prop­yl)amine-κ(3) N,N′,N′′](thio­cyanato-κN)cadmium]-μ(4)-sulfato-κ(4) O,O:O′,O′] methanol hemisolvate]
title_full catena-Poly[[bis­[[bis­(3-amino­prop­yl)amine-κ(3) N,N′,N′′](thio­cyanato-κN)cadmium]-μ(4)-sulfato-κ(4) O,O:O′,O′] methanol hemisolvate]
title_fullStr catena-Poly[[bis­[[bis­(3-amino­prop­yl)amine-κ(3) N,N′,N′′](thio­cyanato-κN)cadmium]-μ(4)-sulfato-κ(4) O,O:O′,O′] methanol hemisolvate]
title_full_unstemmed catena-Poly[[bis­[[bis­(3-amino­prop­yl)amine-κ(3) N,N′,N′′](thio­cyanato-κN)cadmium]-μ(4)-sulfato-κ(4) O,O:O′,O′] methanol hemisolvate]
title_short catena-Poly[[bis­[[bis­(3-amino­prop­yl)amine-κ(3) N,N′,N′′](thio­cyanato-κN)cadmium]-μ(4)-sulfato-κ(4) O,O:O′,O′] methanol hemisolvate]
title_sort catena-poly[[bis­[[bis­(3-amino­prop­yl)amine-κ(3) n,n′,n′′](thio­cyanato-κn)cadmium]-μ(4)-sulfato-κ(4) o,o:o′,o′] methanol hemisolvate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200697/
https://www.ncbi.nlm.nih.gov/pubmed/22058845
http://dx.doi.org/10.1107/S1600536811031163
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