trans-Diaqua­bis­(dl-valinato-κ(2) N,O)nickel(II)

In the title complex, [Ni(C(5)H(9)NO(2))(2)(H(2)O)(2)], the Ni(II) atom, located on a centre of inversion, is trans-coordinated by two O atoms and two N atoms from d-bidentate valine and l-bidentate valine ligands and two water O atoms in an octa­hedral geometry. In the crystal, the discrete mononuc...

Descripción completa

Detalles Bibliográficos
Autores principales: Messai, Amel, Benali-Cherif, Rim, Jeanneau, Erwann, Benali-Cherif, Nourredine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200705/
https://www.ncbi.nlm.nih.gov/pubmed/22065415
http://dx.doi.org/10.1107/S1600536811031072
_version_ 1782214730792828928
author Messai, Amel
Benali-Cherif, Rim
Jeanneau, Erwann
Benali-Cherif, Nourredine
author_facet Messai, Amel
Benali-Cherif, Rim
Jeanneau, Erwann
Benali-Cherif, Nourredine
author_sort Messai, Amel
collection PubMed
description In the title complex, [Ni(C(5)H(9)NO(2))(2)(H(2)O)(2)], the Ni(II) atom, located on a centre of inversion, is trans-coordinated by two O atoms and two N atoms from d-bidentate valine and l-bidentate valine ligands and two water O atoms in an octa­hedral geometry. In the crystal, the discrete mononuclear units are linked into a three-dimensional network via O—H⋯O and N—H⋯O hydrogen bonds. C—H⋯O inter­actions are also observed.
format Online
Article
Text
id pubmed-3200705
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32007052011-11-06 trans-Diaqua­bis­(dl-valinato-κ(2) N,O)nickel(II) Messai, Amel Benali-Cherif, Rim Jeanneau, Erwann Benali-Cherif, Nourredine Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(5)H(9)NO(2))(2)(H(2)O)(2)], the Ni(II) atom, located on a centre of inversion, is trans-coordinated by two O atoms and two N atoms from d-bidentate valine and l-bidentate valine ligands and two water O atoms in an octa­hedral geometry. In the crystal, the discrete mononuclear units are linked into a three-dimensional network via O—H⋯O and N—H⋯O hydrogen bonds. C—H⋯O inter­actions are also observed. International Union of Crystallography 2011-08-06 /pmc/articles/PMC3200705/ /pubmed/22065415 http://dx.doi.org/10.1107/S1600536811031072 Text en © Messai et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Messai, Amel
Benali-Cherif, Rim
Jeanneau, Erwann
Benali-Cherif, Nourredine
trans-Diaqua­bis­(dl-valinato-κ(2) N,O)nickel(II)
title trans-Diaqua­bis­(dl-valinato-κ(2) N,O)nickel(II)
title_full trans-Diaqua­bis­(dl-valinato-κ(2) N,O)nickel(II)
title_fullStr trans-Diaqua­bis­(dl-valinato-κ(2) N,O)nickel(II)
title_full_unstemmed trans-Diaqua­bis­(dl-valinato-κ(2) N,O)nickel(II)
title_short trans-Diaqua­bis­(dl-valinato-κ(2) N,O)nickel(II)
title_sort trans-diaqua­bis­(dl-valinato-κ(2) n,o)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200705/
https://www.ncbi.nlm.nih.gov/pubmed/22065415
http://dx.doi.org/10.1107/S1600536811031072
work_keys_str_mv AT messaiamel transdiaquabisdlvalinatok2nonickelii
AT benalicherifrim transdiaquabisdlvalinatok2nonickelii
AT jeanneauerwann transdiaquabisdlvalinatok2nonickelii
AT benalicherifnourredine transdiaquabisdlvalinatok2nonickelii

Ejemplares similares