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(E)-3-Hydroxy-5,5-dimethyl-2-(3-phenylprop-2-en-1-yl)cyclohex-2-en-1-one
Five of the atoms of the six-membered cyclohexene ring of the title compound, C(17)H(20)O(2), are essentially coplanar (r.m.s. deviation = 0.006 Å), with the sixth (the dimethylmethyl C atom) deviating from the mean plane of the five atoms by 0.610 (2) Å. This plane is nearly perpendicular to the...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200708/ https://www.ncbi.nlm.nih.gov/pubmed/22058958 http://dx.doi.org/10.1107/S160053681103220X |
Sumario: | Five of the atoms of the six-membered cyclohexene ring of the title compound, C(17)H(20)O(2), are essentially coplanar (r.m.s. deviation = 0.006 Å), with the sixth (the dimethylmethyl C atom) deviating from the mean plane of the five atoms by 0.610 (2) Å. This plane is nearly perpendicular to the cinnamyl portion, the two planes being aligned at 85.1 (1)°. Two molecules are linked by an O—H⋯O hydrogen bond about a center of inversion. The cyclohexene ring is disordered over two directly overlapping positions. As a result, the hydroxy group and the keto O atom cannot be distinguished from one another. |
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