Cargando…

Bis[4-(1-imino­eth­yl)-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,N (4)]copper(II)

In the title complex, [Cu(C(12)H(12)N(3)O)(2)], the Cu(II) ion is tetra­coordinated by two N atoms and two O atoms from two bis-chelating 4-(1-imino­eth­yl)-3-methyl-1-phenyl-1H-pyrazol-5-olate ligands in a square-planar geometry. The two N atoms and two O atoms around the Cu(II) atom are trans to e...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhu, Hualing, Wang, Zhan, Wei, Zhen, Bai, Yanan, Xv, Xiaoping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200712/
https://www.ncbi.nlm.nih.gov/pubmed/22058848
http://dx.doi.org/10.1107/S1600536811030753
_version_ 1782214732403441664
author Zhu, Hualing
Wang, Zhan
Wei, Zhen
Bai, Yanan
Xv, Xiaoping
author_facet Zhu, Hualing
Wang, Zhan
Wei, Zhen
Bai, Yanan
Xv, Xiaoping
author_sort Zhu, Hualing
collection PubMed
description In the title complex, [Cu(C(12)H(12)N(3)O)(2)], the Cu(II) ion is tetra­coordinated by two N atoms and two O atoms from two bis-chelating 4-(1-imino­eth­yl)-3-methyl-1-phenyl-1H-pyrazol-5-olate ligands in a square-planar geometry. The two N atoms and two O atoms around the Cu(II) atom are trans to each other, as the Cu(II) atom lies on an inversion centre. The six-membered ring composed of the Cu, an O, an N and three C atoms of the ligand and the pyrazole ring is nearly planar, the largest deviation being 0.037 (4) Å for an N atom. In the crystal, weak inter­molecular C—H⋯N hydrogen-bonding inter­actions link the mol­ecules into chains along the c axis.
format Online
Article
Text
id pubmed-3200712
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32007122011-11-06 Bis[4-(1-imino­eth­yl)-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,N (4)]copper(II) Zhu, Hualing Wang, Zhan Wei, Zhen Bai, Yanan Xv, Xiaoping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(12)H(12)N(3)O)(2)], the Cu(II) ion is tetra­coordinated by two N atoms and two O atoms from two bis-chelating 4-(1-imino­eth­yl)-3-methyl-1-phenyl-1H-pyrazol-5-olate ligands in a square-planar geometry. The two N atoms and two O atoms around the Cu(II) atom are trans to each other, as the Cu(II) atom lies on an inversion centre. The six-membered ring composed of the Cu, an O, an N and three C atoms of the ligand and the pyrazole ring is nearly planar, the largest deviation being 0.037 (4) Å for an N atom. In the crystal, weak inter­molecular C—H⋯N hydrogen-bonding inter­actions link the mol­ecules into chains along the c axis. International Union of Crystallography 2011-08-06 /pmc/articles/PMC3200712/ /pubmed/22058848 http://dx.doi.org/10.1107/S1600536811030753 Text en © Zhu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Hualing
Wang, Zhan
Wei, Zhen
Bai, Yanan
Xv, Xiaoping
Bis[4-(1-imino­eth­yl)-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,N (4)]copper(II)
title Bis[4-(1-imino­eth­yl)-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,N (4)]copper(II)
title_full Bis[4-(1-imino­eth­yl)-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,N (4)]copper(II)
title_fullStr Bis[4-(1-imino­eth­yl)-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,N (4)]copper(II)
title_full_unstemmed Bis[4-(1-imino­eth­yl)-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,N (4)]copper(II)
title_short Bis[4-(1-imino­eth­yl)-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,N (4)]copper(II)
title_sort bis[4-(1-imino­eth­yl)-3-methyl-1-phenyl-1h-pyrazol-5-olato-κ(2) o,n (4)]copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200712/
https://www.ncbi.nlm.nih.gov/pubmed/22058848
http://dx.doi.org/10.1107/S1600536811030753
work_keys_str_mv AT zhuhualing bis41iminoethyl3methyl1phenyl1hpyrazol5olatok2on4copperii
AT wangzhan bis41iminoethyl3methyl1phenyl1hpyrazol5olatok2on4copperii
AT weizhen bis41iminoethyl3methyl1phenyl1hpyrazol5olatok2on4copperii
AT baiyanan bis41iminoethyl3methyl1phenyl1hpyrazol5olatok2on4copperii
AT xvxiaoping bis41iminoethyl3methyl1phenyl1hpyrazol5olatok2on4copperii