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Bis[4-(1-iminoethyl)-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,N (4)]copper(II)
In the title complex, [Cu(C(12)H(12)N(3)O)(2)], the Cu(II) ion is tetracoordinated by two N atoms and two O atoms from two bis-chelating 4-(1-iminoethyl)-3-methyl-1-phenyl-1H-pyrazol-5-olate ligands in a square-planar geometry. The two N atoms and two O atoms around the Cu(II) atom are trans to e...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200712/ https://www.ncbi.nlm.nih.gov/pubmed/22058848 http://dx.doi.org/10.1107/S1600536811030753 |
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author | Zhu, Hualing Wang, Zhan Wei, Zhen Bai, Yanan Xv, Xiaoping |
author_facet | Zhu, Hualing Wang, Zhan Wei, Zhen Bai, Yanan Xv, Xiaoping |
author_sort | Zhu, Hualing |
collection | PubMed |
description | In the title complex, [Cu(C(12)H(12)N(3)O)(2)], the Cu(II) ion is tetracoordinated by two N atoms and two O atoms from two bis-chelating 4-(1-iminoethyl)-3-methyl-1-phenyl-1H-pyrazol-5-olate ligands in a square-planar geometry. The two N atoms and two O atoms around the Cu(II) atom are trans to each other, as the Cu(II) atom lies on an inversion centre. The six-membered ring composed of the Cu, an O, an N and three C atoms of the ligand and the pyrazole ring is nearly planar, the largest deviation being 0.037 (4) Å for an N atom. In the crystal, weak intermolecular C—H⋯N hydrogen-bonding interactions link the molecules into chains along the c axis. |
format | Online Article Text |
id | pubmed-3200712 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32007122011-11-06 Bis[4-(1-iminoethyl)-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,N (4)]copper(II) Zhu, Hualing Wang, Zhan Wei, Zhen Bai, Yanan Xv, Xiaoping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(12)H(12)N(3)O)(2)], the Cu(II) ion is tetracoordinated by two N atoms and two O atoms from two bis-chelating 4-(1-iminoethyl)-3-methyl-1-phenyl-1H-pyrazol-5-olate ligands in a square-planar geometry. The two N atoms and two O atoms around the Cu(II) atom are trans to each other, as the Cu(II) atom lies on an inversion centre. The six-membered ring composed of the Cu, an O, an N and three C atoms of the ligand and the pyrazole ring is nearly planar, the largest deviation being 0.037 (4) Å for an N atom. In the crystal, weak intermolecular C—H⋯N hydrogen-bonding interactions link the molecules into chains along the c axis. International Union of Crystallography 2011-08-06 /pmc/articles/PMC3200712/ /pubmed/22058848 http://dx.doi.org/10.1107/S1600536811030753 Text en © Zhu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhu, Hualing Wang, Zhan Wei, Zhen Bai, Yanan Xv, Xiaoping Bis[4-(1-iminoethyl)-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,N (4)]copper(II) |
title | Bis[4-(1-iminoethyl)-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2)
O,N
(4)]copper(II) |
title_full | Bis[4-(1-iminoethyl)-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2)
O,N
(4)]copper(II) |
title_fullStr | Bis[4-(1-iminoethyl)-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2)
O,N
(4)]copper(II) |
title_full_unstemmed | Bis[4-(1-iminoethyl)-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2)
O,N
(4)]copper(II) |
title_short | Bis[4-(1-iminoethyl)-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2)
O,N
(4)]copper(II) |
title_sort | bis[4-(1-iminoethyl)-3-methyl-1-phenyl-1h-pyrazol-5-olato-κ(2)
o,n
(4)]copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200712/ https://www.ncbi.nlm.nih.gov/pubmed/22058848 http://dx.doi.org/10.1107/S1600536811030753 |
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