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catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)yttrium(III)] [silver(I)-di-μ-sulfido-molybdenum(VI)-di-μ-sulfido]]

In the cation of the title compound, {[Y(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgMoS(4)]}(n), the Y atom is coordinated by eight O atoms from two chelating nitrate groups and four hexa­methyl­phospho­ramide (hmp) ligands, which gives rise to a distorted square-anti­prismatic environment. Together with the...

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Detalles Bibliográficos
Autor principal: Zhang, Jinfang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200717/
https://www.ncbi.nlm.nih.gov/pubmed/22065643
http://dx.doi.org/10.1107/S1600536811030996
Descripción
Sumario:In the cation of the title compound, {[Y(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgMoS(4)]}(n), the Y atom is coordinated by eight O atoms from two chelating nitrate groups and four hexa­methyl­phospho­ramide (hmp) ligands, which gives rise to a distorted square-anti­prismatic environment. Together with the two nitrate ligands, the overall charge for the complex cation is +1, which leads to the anionic chain having a monovalent repeat unit. The polymeric anionic chain, with Mo—Ag—Mo and Ag—Mo—Ag angles of 161.916 (13) and 153.915 (13)°, respectively, presents a distorted linear configuration. The cations and the anions are linked via weak C—H⋯S hydrogen-bonding inter­actions while the cations exhibit inter­molecular C—H⋯O inter­actions. The structure is isotypic with the corresponding W, Yb, Eu, Nd, La and Dy complexes.