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catena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato-κ(2) O,O′)yttrium(III)] [silver(I)-di-μ-sulfido-molybdenum(VI)-di-μ-sulfido]]
In the cation of the title compound, {[Y(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgMoS(4)]}(n), the Y atom is coordinated by eight O atoms from two chelating nitrate groups and four hexamethylphosphoramide (hmp) ligands, which gives rise to a distorted square-antiprismatic environment. Together with the...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200717/ https://www.ncbi.nlm.nih.gov/pubmed/22065643 http://dx.doi.org/10.1107/S1600536811030996 |
Sumario: | In the cation of the title compound, {[Y(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgMoS(4)]}(n), the Y atom is coordinated by eight O atoms from two chelating nitrate groups and four hexamethylphosphoramide (hmp) ligands, which gives rise to a distorted square-antiprismatic environment. Together with the two nitrate ligands, the overall charge for the complex cation is +1, which leads to the anionic chain having a monovalent repeat unit. The polymeric anionic chain, with Mo—Ag—Mo and Ag—Mo—Ag angles of 161.916 (13) and 153.915 (13)°, respectively, presents a distorted linear configuration. The cations and the anions are linked via weak C—H⋯S hydrogen-bonding interactions while the cations exhibit intermolecular C—H⋯O interactions. The structure is isotypic with the corresponding W, Yb, Eu, Nd, La and Dy complexes. |
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