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catena-Poly[[tetrakis(μ-pentafluorobenzoato-κ(2) O:O′)dimolybdenum(II)]-μ-4,4′-bipyridine-κ(2) N:N′]
In the title compound, [Mo(2)(C(7)F(5)O(2))(4)(C(10)H(8)N(2))](n), the molecule forms a paddle-wheel-type structure. Each Mo(2) (4+) unit is equatorially coordinated by four pentafluorobenzoate groups, while the axial positions are occupied by two 4,4′-bipyridine molecules. The Mo—Mo bond length...
Autor principal: | |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200718/ https://www.ncbi.nlm.nih.gov/pubmed/22058859 http://dx.doi.org/10.1107/S1600536811031734 |
Sumario: | In the title compound, [Mo(2)(C(7)F(5)O(2))(4)(C(10)H(8)N(2))](n), the molecule forms a paddle-wheel-type structure. Each Mo(2) (4+) unit is equatorially coordinated by four pentafluorobenzoate groups, while the axial positions are occupied by two 4,4′-bipyridine molecules. The Mo—Mo bond length of 2.1227 (4) Å is representative of a dimolybdenum quadruple bond. An infinite linear chain parallel to [110] is formed by the Mo(2) (4+) unit coordinating axially to the two N atoms of the 4,4′-bipyridine ligand [Mo—N = 2.594 (2) Å]. The crystal packing shows molecules linked together into a three-dimensional network via Mo—N coordination interactions and weak π–π stacking interactions between perfluorophenyl rings [centroid–centroid distance = 3.7280 (3) Å and centroid-to-plane distance = 3.6103 (12) Å between two pentafluorophenyl rings]. |
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