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catena-Poly[[tetra­kis­(μ-penta­fluoro­benzoato-κ(2) O:O′)dimolybdenum(II)]-μ-4,4′-bipyridine-κ(2) N:N′]

In the title compound, [Mo(2)(C(7)F(5)O(2))(4)(C(10)H(8)N(2))](n), the mol­ecule forms a paddle-wheel-type structure. Each Mo(2) (4+) unit is equatorially coordinated by four pentafluoro­benzoate groups, while the axial positions are occupied by two 4,4′-bipyridine mol­ecules. The Mo—Mo bond length...

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Autor principal: Han, Li-Juan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200718/
https://www.ncbi.nlm.nih.gov/pubmed/22058859
http://dx.doi.org/10.1107/S1600536811031734
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author Han, Li-Juan
author_facet Han, Li-Juan
author_sort Han, Li-Juan
collection PubMed
description In the title compound, [Mo(2)(C(7)F(5)O(2))(4)(C(10)H(8)N(2))](n), the mol­ecule forms a paddle-wheel-type structure. Each Mo(2) (4+) unit is equatorially coordinated by four pentafluoro­benzoate groups, while the axial positions are occupied by two 4,4′-bipyridine mol­ecules. The Mo—Mo bond length of 2.1227 (4) Å is representative of a dimolybdenum quadruple bond. An infinite linear chain parallel to [110] is formed by the Mo(2) (4+) unit coordinating axially to the two N atoms of the 4,4′-bipyridine ligand [Mo—N = 2.594 (2) Å]. The crystal packing shows mol­ecules linked together into a three-dimensional network via Mo—N coordination inter­actions and weak π–π stacking inter­actions between perfluoro­phenyl rings [centroid–centroid distance = 3.7280 (3) Å and centroid-to-plane distance = 3.6103 (12) Å between two penta­fluoro­phenyl rings].
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spelling pubmed-32007182011-11-06 catena-Poly[[tetra­kis­(μ-penta­fluoro­benzoato-κ(2) O:O′)dimolybdenum(II)]-μ-4,4′-bipyridine-κ(2) N:N′] Han, Li-Juan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mo(2)(C(7)F(5)O(2))(4)(C(10)H(8)N(2))](n), the mol­ecule forms a paddle-wheel-type structure. Each Mo(2) (4+) unit is equatorially coordinated by four pentafluoro­benzoate groups, while the axial positions are occupied by two 4,4′-bipyridine mol­ecules. The Mo—Mo bond length of 2.1227 (4) Å is representative of a dimolybdenum quadruple bond. An infinite linear chain parallel to [110] is formed by the Mo(2) (4+) unit coordinating axially to the two N atoms of the 4,4′-bipyridine ligand [Mo—N = 2.594 (2) Å]. The crystal packing shows mol­ecules linked together into a three-dimensional network via Mo—N coordination inter­actions and weak π–π stacking inter­actions between perfluoro­phenyl rings [centroid–centroid distance = 3.7280 (3) Å and centroid-to-plane distance = 3.6103 (12) Å between two penta­fluoro­phenyl rings]. International Union of Crystallography 2011-08-17 /pmc/articles/PMC3200718/ /pubmed/22058859 http://dx.doi.org/10.1107/S1600536811031734 Text en © L.-J. Han 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Han, Li-Juan
catena-Poly[[tetra­kis­(μ-penta­fluoro­benzoato-κ(2) O:O′)dimolybdenum(II)]-μ-4,4′-bipyridine-κ(2) N:N′]
title catena-Poly[[tetra­kis­(μ-penta­fluoro­benzoato-κ(2) O:O′)dimolybdenum(II)]-μ-4,4′-bipyridine-κ(2) N:N′]
title_full catena-Poly[[tetra­kis­(μ-penta­fluoro­benzoato-κ(2) O:O′)dimolybdenum(II)]-μ-4,4′-bipyridine-κ(2) N:N′]
title_fullStr catena-Poly[[tetra­kis­(μ-penta­fluoro­benzoato-κ(2) O:O′)dimolybdenum(II)]-μ-4,4′-bipyridine-κ(2) N:N′]
title_full_unstemmed catena-Poly[[tetra­kis­(μ-penta­fluoro­benzoato-κ(2) O:O′)dimolybdenum(II)]-μ-4,4′-bipyridine-κ(2) N:N′]
title_short catena-Poly[[tetra­kis­(μ-penta­fluoro­benzoato-κ(2) O:O′)dimolybdenum(II)]-μ-4,4′-bipyridine-κ(2) N:N′]
title_sort catena-poly[[tetra­kis­(μ-penta­fluoro­benzoato-κ(2) o:o′)dimolybdenum(ii)]-μ-4,4′-bipyridine-κ(2) n:n′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200718/
https://www.ncbi.nlm.nih.gov/pubmed/22058859
http://dx.doi.org/10.1107/S1600536811031734
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