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catena-Poly[[tetrakis(μ-pentafluorobenzoato-κ(2) O:O′)dimolybdenum(II)]-μ-4,4′-bipyridine-κ(2) N:N′]
In the title compound, [Mo(2)(C(7)F(5)O(2))(4)(C(10)H(8)N(2))](n), the molecule forms a paddle-wheel-type structure. Each Mo(2) (4+) unit is equatorially coordinated by four pentafluorobenzoate groups, while the axial positions are occupied by two 4,4′-bipyridine molecules. The Mo—Mo bond length...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200718/ https://www.ncbi.nlm.nih.gov/pubmed/22058859 http://dx.doi.org/10.1107/S1600536811031734 |
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author | Han, Li-Juan |
author_facet | Han, Li-Juan |
author_sort | Han, Li-Juan |
collection | PubMed |
description | In the title compound, [Mo(2)(C(7)F(5)O(2))(4)(C(10)H(8)N(2))](n), the molecule forms a paddle-wheel-type structure. Each Mo(2) (4+) unit is equatorially coordinated by four pentafluorobenzoate groups, while the axial positions are occupied by two 4,4′-bipyridine molecules. The Mo—Mo bond length of 2.1227 (4) Å is representative of a dimolybdenum quadruple bond. An infinite linear chain parallel to [110] is formed by the Mo(2) (4+) unit coordinating axially to the two N atoms of the 4,4′-bipyridine ligand [Mo—N = 2.594 (2) Å]. The crystal packing shows molecules linked together into a three-dimensional network via Mo—N coordination interactions and weak π–π stacking interactions between perfluorophenyl rings [centroid–centroid distance = 3.7280 (3) Å and centroid-to-plane distance = 3.6103 (12) Å between two pentafluorophenyl rings]. |
format | Online Article Text |
id | pubmed-3200718 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32007182011-11-06 catena-Poly[[tetrakis(μ-pentafluorobenzoato-κ(2) O:O′)dimolybdenum(II)]-μ-4,4′-bipyridine-κ(2) N:N′] Han, Li-Juan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mo(2)(C(7)F(5)O(2))(4)(C(10)H(8)N(2))](n), the molecule forms a paddle-wheel-type structure. Each Mo(2) (4+) unit is equatorially coordinated by four pentafluorobenzoate groups, while the axial positions are occupied by two 4,4′-bipyridine molecules. The Mo—Mo bond length of 2.1227 (4) Å is representative of a dimolybdenum quadruple bond. An infinite linear chain parallel to [110] is formed by the Mo(2) (4+) unit coordinating axially to the two N atoms of the 4,4′-bipyridine ligand [Mo—N = 2.594 (2) Å]. The crystal packing shows molecules linked together into a three-dimensional network via Mo—N coordination interactions and weak π–π stacking interactions between perfluorophenyl rings [centroid–centroid distance = 3.7280 (3) Å and centroid-to-plane distance = 3.6103 (12) Å between two pentafluorophenyl rings]. International Union of Crystallography 2011-08-17 /pmc/articles/PMC3200718/ /pubmed/22058859 http://dx.doi.org/10.1107/S1600536811031734 Text en © L.-J. Han 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Han, Li-Juan catena-Poly[[tetrakis(μ-pentafluorobenzoato-κ(2) O:O′)dimolybdenum(II)]-μ-4,4′-bipyridine-κ(2) N:N′] |
title |
catena-Poly[[tetrakis(μ-pentafluorobenzoato-κ(2)
O:O′)dimolybdenum(II)]-μ-4,4′-bipyridine-κ(2)
N:N′] |
title_full |
catena-Poly[[tetrakis(μ-pentafluorobenzoato-κ(2)
O:O′)dimolybdenum(II)]-μ-4,4′-bipyridine-κ(2)
N:N′] |
title_fullStr |
catena-Poly[[tetrakis(μ-pentafluorobenzoato-κ(2)
O:O′)dimolybdenum(II)]-μ-4,4′-bipyridine-κ(2)
N:N′] |
title_full_unstemmed |
catena-Poly[[tetrakis(μ-pentafluorobenzoato-κ(2)
O:O′)dimolybdenum(II)]-μ-4,4′-bipyridine-κ(2)
N:N′] |
title_short |
catena-Poly[[tetrakis(μ-pentafluorobenzoato-κ(2)
O:O′)dimolybdenum(II)]-μ-4,4′-bipyridine-κ(2)
N:N′] |
title_sort | catena-poly[[tetrakis(μ-pentafluorobenzoato-κ(2)
o:o′)dimolybdenum(ii)]-μ-4,4′-bipyridine-κ(2)
n:n′] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200718/ https://www.ncbi.nlm.nih.gov/pubmed/22058859 http://dx.doi.org/10.1107/S1600536811031734 |
work_keys_str_mv | AT hanlijuan catenapolytetrakismpentafluorobenzoatok2oodimolybdenumiim44bipyridinek2nn |