Dichloridotetra­kis­(diniconazole)cobalt(II)

In the crystal structure of the title compound, [CoCl(2)(C(15)H(17)Cl(2)N(3)O)(4)], the Co(II) cation lies on an inversion center and has a slightly distorted octa­hedral coordination geometry. The equatorial positions are occupied by four N atoms from four diniconazole [systematic name: (E)-(RS)-1-...

Descripción completa

Detalles Bibliográficos
Autores principales: Liu, Chang-Xiang, Song, Xiu-Ying, Liu, Qian, Nie, Xu-Liang, Wen, Shi-He
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200721/
https://www.ncbi.nlm.nih.gov/pubmed/22065723
http://dx.doi.org/10.1107/S1600536811031291
Descripción
Sumario:In the crystal structure of the title compound, [CoCl(2)(C(15)H(17)Cl(2)N(3)O)(4)], the Co(II) cation lies on an inversion center and has a slightly distorted octa­hedral coordination geometry. The equatorial positions are occupied by four N atoms from four diniconazole [systematic name: (E)-(RS)-1-(2,4-dichloro­phen­yl)-4,4-dimethyl-2-(1H-1,2,4-triazol-1-yl)pent-1-en-3-ol] ligands. The axial sites are occupied by two Cl(−) anions. In the two independent organic ligands, the triazole ring is oriented at dihedral angles of 18.28 (14) and 32.15 (14)° with respect to the dichloro­phenyl ring. Inter­molecular O—H⋯Cl hydrogen bonds consolidate the crystal packing.

Ejemplares similares