Dichloridotetra­kis­(diniconazole)cobalt(II)

In the crystal structure of the title compound, [CoCl(2)(C(15)H(17)Cl(2)N(3)O)(4)], the Co(II) cation lies on an inversion center and has a slightly distorted octa­hedral coordination geometry. The equatorial positions are occupied by four N atoms from four diniconazole [systematic name: (E)-(RS)-1-...

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Autores principales: Liu, Chang-Xiang, Song, Xiu-Ying, Liu, Qian, Nie, Xu-Liang, Wen, Shi-He
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200721/
https://www.ncbi.nlm.nih.gov/pubmed/22065723
http://dx.doi.org/10.1107/S1600536811031291
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author Liu, Chang-Xiang
Song, Xiu-Ying
Liu, Qian
Nie, Xu-Liang
Wen, Shi-He
author_facet Liu, Chang-Xiang
Song, Xiu-Ying
Liu, Qian
Nie, Xu-Liang
Wen, Shi-He
author_sort Liu, Chang-Xiang
collection PubMed
description In the crystal structure of the title compound, [CoCl(2)(C(15)H(17)Cl(2)N(3)O)(4)], the Co(II) cation lies on an inversion center and has a slightly distorted octa­hedral coordination geometry. The equatorial positions are occupied by four N atoms from four diniconazole [systematic name: (E)-(RS)-1-(2,4-dichloro­phen­yl)-4,4-dimethyl-2-(1H-1,2,4-triazol-1-yl)pent-1-en-3-ol] ligands. The axial sites are occupied by two Cl(−) anions. In the two independent organic ligands, the triazole ring is oriented at dihedral angles of 18.28 (14) and 32.15 (14)° with respect to the dichloro­phenyl ring. Inter­molecular O—H⋯Cl hydrogen bonds consolidate the crystal packing.
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spelling pubmed-32007212011-11-06 Dichloridotetra­kis­(diniconazole)cobalt(II) Liu, Chang-Xiang Song, Xiu-Ying Liu, Qian Nie, Xu-Liang Wen, Shi-He Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [CoCl(2)(C(15)H(17)Cl(2)N(3)O)(4)], the Co(II) cation lies on an inversion center and has a slightly distorted octa­hedral coordination geometry. The equatorial positions are occupied by four N atoms from four diniconazole [systematic name: (E)-(RS)-1-(2,4-dichloro­phen­yl)-4,4-dimethyl-2-(1H-1,2,4-triazol-1-yl)pent-1-en-3-ol] ligands. The axial sites are occupied by two Cl(−) anions. In the two independent organic ligands, the triazole ring is oriented at dihedral angles of 18.28 (14) and 32.15 (14)° with respect to the dichloro­phenyl ring. Inter­molecular O—H⋯Cl hydrogen bonds consolidate the crystal packing. International Union of Crystallography 2011-08-11 /pmc/articles/PMC3200721/ /pubmed/22065723 http://dx.doi.org/10.1107/S1600536811031291 Text en © Liu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Chang-Xiang
Song, Xiu-Ying
Liu, Qian
Nie, Xu-Liang
Wen, Shi-He
Dichloridotetra­kis­(diniconazole)cobalt(II)
title Dichloridotetra­kis­(diniconazole)cobalt(II)
title_full Dichloridotetra­kis­(diniconazole)cobalt(II)
title_fullStr Dichloridotetra­kis­(diniconazole)cobalt(II)
title_full_unstemmed Dichloridotetra­kis­(diniconazole)cobalt(II)
title_short Dichloridotetra­kis­(diniconazole)cobalt(II)
title_sort dichloridotetra­kis­(diniconazole)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200721/
https://www.ncbi.nlm.nih.gov/pubmed/22065723
http://dx.doi.org/10.1107/S1600536811031291
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AT niexuliang dichloridotetrakisdiniconazolecobaltii
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