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Triprolidinium dipicrate
In the tripodinium cation of the title compound {systematic name: 2-[(E)-1-(4-methylphenyl)-3-(pyrrolidin-1-ium-1-yl)prop-1-enyl]pyridinium bis(2,4,6-trinitrophenolate)}, C(19)H(24)N(2) (+)·2C(6)H(2)N(3)O(7) (−), the N atoms on both the pyrrolidine and pyridinium groups are protonated. The pyrr...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200727/ https://www.ncbi.nlm.nih.gov/pubmed/22064274 http://dx.doi.org/10.1107/S160053681103457X |
Sumario: | In the tripodinium cation of the title compound {systematic name: 2-[(E)-1-(4-methylphenyl)-3-(pyrrolidin-1-ium-1-yl)prop-1-enyl]pyridinium bis(2,4,6-trinitrophenolate)}, C(19)H(24)N(2) (+)·2C(6)H(2)N(3)O(7) (−), the N atoms on both the pyrrolidine and pyridinium groups are protonated. The pyrrolidine group adopts a slightly distorted envelope configuration. Strong N—H⋯O cation–anion hydrogen bonds and weak intermolecular N—H⋯O interactions link the dication and two anions. In both picrate anions, the nitro groups display rotational disorder over two orientations in a 0.605 (6):0.395 (6) ratio. The crystal packing also features weak intermolecular π–π [centroid–centroid distance = 3.8036 (14) Å] and C—H⋯O interactions. |
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