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Triprolidinium dipicrate

In the tripodinium cation of the title compound {systematic name: 2-[(E)-1-(4-methyl­phen­yl)-3-(pyrrolidin-1-ium-1-yl)prop-1-en­yl]pyridinium bis­(2,4,6-trinitro­phenolate)}, C(19)H(24)N(2) (+)·2C(6)H(2)N(3)O(7) (−), the N atoms on both the pyrrolidine and pyridinium groups are protonated. The pyrr...

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Autores principales: Dayananda, A. S., Jasinski, Jerry P., Golen, James A., Yathirajan, H. S., Raju, C. R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200727/
https://www.ncbi.nlm.nih.gov/pubmed/22064274
http://dx.doi.org/10.1107/S160053681103457X
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author Dayananda, A. S.
Jasinski, Jerry P.
Golen, James A.
Yathirajan, H. S.
Raju, C. R.
author_facet Dayananda, A. S.
Jasinski, Jerry P.
Golen, James A.
Yathirajan, H. S.
Raju, C. R.
author_sort Dayananda, A. S.
collection PubMed
description In the tripodinium cation of the title compound {systematic name: 2-[(E)-1-(4-methyl­phen­yl)-3-(pyrrolidin-1-ium-1-yl)prop-1-en­yl]pyridinium bis­(2,4,6-trinitro­phenolate)}, C(19)H(24)N(2) (+)·2C(6)H(2)N(3)O(7) (−), the N atoms on both the pyrrolidine and pyridinium groups are protonated. The pyrrolidine group adopts a slightly distorted envelope configuration. Strong N—H⋯O cation–anion hydrogen bonds and weak inter­molecular N—H⋯O inter­actions link the dication and two anions. In both picrate anions, the nitro groups display rotational disorder over two orientations in a 0.605 (6):0.395 (6) ratio. The crystal packing also features weak inter­molecular π–π [centroid–centroid distance = 3.8036 (14) Å] and C—H⋯O inter­actions.
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spelling pubmed-32007272011-11-06 Triprolidinium dipicrate Dayananda, A. S. Jasinski, Jerry P. Golen, James A. Yathirajan, H. S. Raju, C. R. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the tripodinium cation of the title compound {systematic name: 2-[(E)-1-(4-methyl­phen­yl)-3-(pyrrolidin-1-ium-1-yl)prop-1-en­yl]pyridinium bis­(2,4,6-trinitro­phenolate)}, C(19)H(24)N(2) (+)·2C(6)H(2)N(3)O(7) (−), the N atoms on both the pyrrolidine and pyridinium groups are protonated. The pyrrolidine group adopts a slightly distorted envelope configuration. Strong N—H⋯O cation–anion hydrogen bonds and weak inter­molecular N—H⋯O inter­actions link the dication and two anions. In both picrate anions, the nitro groups display rotational disorder over two orientations in a 0.605 (6):0.395 (6) ratio. The crystal packing also features weak inter­molecular π–π [centroid–centroid distance = 3.8036 (14) Å] and C—H⋯O inter­actions. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200727/ /pubmed/22064274 http://dx.doi.org/10.1107/S160053681103457X Text en © Dayananda et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Dayananda, A. S.
Jasinski, Jerry P.
Golen, James A.
Yathirajan, H. S.
Raju, C. R.
Triprolidinium dipicrate
title Triprolidinium dipicrate
title_full Triprolidinium dipicrate
title_fullStr Triprolidinium dipicrate
title_full_unstemmed Triprolidinium dipicrate
title_short Triprolidinium dipicrate
title_sort triprolidinium dipicrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200727/
https://www.ncbi.nlm.nih.gov/pubmed/22064274
http://dx.doi.org/10.1107/S160053681103457X
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