Cargando…
Triprolidinium dipicrate
In the tripodinium cation of the title compound {systematic name: 2-[(E)-1-(4-methylphenyl)-3-(pyrrolidin-1-ium-1-yl)prop-1-enyl]pyridinium bis(2,4,6-trinitrophenolate)}, C(19)H(24)N(2) (+)·2C(6)H(2)N(3)O(7) (−), the N atoms on both the pyrrolidine and pyridinium groups are protonated. The pyrr...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200727/ https://www.ncbi.nlm.nih.gov/pubmed/22064274 http://dx.doi.org/10.1107/S160053681103457X |
_version_ | 1782214735818653696 |
---|---|
author | Dayananda, A. S. Jasinski, Jerry P. Golen, James A. Yathirajan, H. S. Raju, C. R. |
author_facet | Dayananda, A. S. Jasinski, Jerry P. Golen, James A. Yathirajan, H. S. Raju, C. R. |
author_sort | Dayananda, A. S. |
collection | PubMed |
description | In the tripodinium cation of the title compound {systematic name: 2-[(E)-1-(4-methylphenyl)-3-(pyrrolidin-1-ium-1-yl)prop-1-enyl]pyridinium bis(2,4,6-trinitrophenolate)}, C(19)H(24)N(2) (+)·2C(6)H(2)N(3)O(7) (−), the N atoms on both the pyrrolidine and pyridinium groups are protonated. The pyrrolidine group adopts a slightly distorted envelope configuration. Strong N—H⋯O cation–anion hydrogen bonds and weak intermolecular N—H⋯O interactions link the dication and two anions. In both picrate anions, the nitro groups display rotational disorder over two orientations in a 0.605 (6):0.395 (6) ratio. The crystal packing also features weak intermolecular π–π [centroid–centroid distance = 3.8036 (14) Å] and C—H⋯O interactions. |
format | Online Article Text |
id | pubmed-3200727 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32007272011-11-06 Triprolidinium dipicrate Dayananda, A. S. Jasinski, Jerry P. Golen, James A. Yathirajan, H. S. Raju, C. R. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the tripodinium cation of the title compound {systematic name: 2-[(E)-1-(4-methylphenyl)-3-(pyrrolidin-1-ium-1-yl)prop-1-enyl]pyridinium bis(2,4,6-trinitrophenolate)}, C(19)H(24)N(2) (+)·2C(6)H(2)N(3)O(7) (−), the N atoms on both the pyrrolidine and pyridinium groups are protonated. The pyrrolidine group adopts a slightly distorted envelope configuration. Strong N—H⋯O cation–anion hydrogen bonds and weak intermolecular N—H⋯O interactions link the dication and two anions. In both picrate anions, the nitro groups display rotational disorder over two orientations in a 0.605 (6):0.395 (6) ratio. The crystal packing also features weak intermolecular π–π [centroid–centroid distance = 3.8036 (14) Å] and C—H⋯O interactions. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200727/ /pubmed/22064274 http://dx.doi.org/10.1107/S160053681103457X Text en © Dayananda et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Dayananda, A. S. Jasinski, Jerry P. Golen, James A. Yathirajan, H. S. Raju, C. R. Triprolidinium dipicrate |
title | Triprolidinium dipicrate |
title_full | Triprolidinium dipicrate |
title_fullStr | Triprolidinium dipicrate |
title_full_unstemmed | Triprolidinium dipicrate |
title_short | Triprolidinium dipicrate |
title_sort | triprolidinium dipicrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200727/ https://www.ncbi.nlm.nih.gov/pubmed/22064274 http://dx.doi.org/10.1107/S160053681103457X |
work_keys_str_mv | AT dayanandaas triprolidiniumdipicrate AT jasinskijerryp triprolidiniumdipicrate AT golenjamesa triprolidiniumdipicrate AT yathirajanhs triprolidiniumdipicrate AT rajucr triprolidiniumdipicrate |