8-Phenyl-3,4,6,7,8,8a-hexahydro-1H-pyrrolo­[2,1-c][1,4]oxazin-6-one

In the title compound, C(13)H(15)NO(2), the hexa­hydro­pyrrolo­[2,1-c][1,4]oxazine fragment is disordered over two conformations (A and B) in a 0.656 (5):0.344 (5) ratio. The five-membered ring is similarly disordered and adopts an envelope conformation in A, while in B this ring is nearly planar [m...

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Detalles Bibliográficos
Autores principales: Małecka, Magdalena, Pasternak, Beata, Leśniak, Stanisław
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200730/
https://www.ncbi.nlm.nih.gov/pubmed/22058987
http://dx.doi.org/10.1107/S1600536811032806
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author Małecka, Magdalena
Pasternak, Beata
Leśniak, Stanisław
author_facet Małecka, Magdalena
Pasternak, Beata
Leśniak, Stanisław
author_sort Małecka, Magdalena
collection PubMed
description In the title compound, C(13)H(15)NO(2), the hexa­hydro­pyrrolo­[2,1-c][1,4]oxazine fragment is disordered over two conformations (A and B) in a 0.656 (5):0.344 (5) ratio. The five-membered ring is similarly disordered and adopts an envelope conformation in A, while in B this ring is nearly planar [maximum deviation = 0.088 (1) Å]. The six-membered rings in both A and B exhibit chair conformations. In the crystal, weak inter­molecular C—H⋯O hydrogen bonds link the mol­ecules into ribbons propagating in [010].
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spelling pubmed-32007302011-11-06 8-Phenyl-3,4,6,7,8,8a-hexahydro-1H-pyrrolo­[2,1-c][1,4]oxazin-6-one Małecka, Magdalena Pasternak, Beata Leśniak, Stanisław Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(15)NO(2), the hexa­hydro­pyrrolo­[2,1-c][1,4]oxazine fragment is disordered over two conformations (A and B) in a 0.656 (5):0.344 (5) ratio. The five-membered ring is similarly disordered and adopts an envelope conformation in A, while in B this ring is nearly planar [maximum deviation = 0.088 (1) Å]. The six-membered rings in both A and B exhibit chair conformations. In the crystal, weak inter­molecular C—H⋯O hydrogen bonds link the mol­ecules into ribbons propagating in [010]. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200730/ /pubmed/22058987 http://dx.doi.org/10.1107/S1600536811032806 Text en © MałeckA et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Małecka, Magdalena
Pasternak, Beata
Leśniak, Stanisław
8-Phenyl-3,4,6,7,8,8a-hexahydro-1H-pyrrolo­[2,1-c][1,4]oxazin-6-one
title 8-Phenyl-3,4,6,7,8,8a-hexahydro-1H-pyrrolo­[2,1-c][1,4]oxazin-6-one
title_full 8-Phenyl-3,4,6,7,8,8a-hexahydro-1H-pyrrolo­[2,1-c][1,4]oxazin-6-one
title_fullStr 8-Phenyl-3,4,6,7,8,8a-hexahydro-1H-pyrrolo­[2,1-c][1,4]oxazin-6-one
title_full_unstemmed 8-Phenyl-3,4,6,7,8,8a-hexahydro-1H-pyrrolo­[2,1-c][1,4]oxazin-6-one
title_short 8-Phenyl-3,4,6,7,8,8a-hexahydro-1H-pyrrolo­[2,1-c][1,4]oxazin-6-one
title_sort 8-phenyl-3,4,6,7,8,8a-hexahydro-1h-pyrrolo­[2,1-c][1,4]oxazin-6-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200730/
https://www.ncbi.nlm.nih.gov/pubmed/22058987
http://dx.doi.org/10.1107/S1600536811032806
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AT lesniakstanisław 8phenyl346788ahexahydro1hpyrrolo21c14oxazin6one

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