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catena-Poly[[aquabis(N (6)-benzyladenine-κN (3))copper(II)]-μ-benzene-1,4-dicarboxylato-κ(2) O (1):O (4)]
In the title compound, [Cu(C(8)H(4)O(4))(C(12)H(11)N(5))(2)(H(2)O)](n), the Cu(II) ion is five-coordinated by two carboxylate O atoms from two symmetry-related benzene-1,4-dicarboxylate ligands, two N atoms from two symmetry-related N (6)-benzyladenine ligands and one water O atom in a square-pyr...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200734/ https://www.ncbi.nlm.nih.gov/pubmed/22058863 http://dx.doi.org/10.1107/S1600536811032168 |
Sumario: | In the title compound, [Cu(C(8)H(4)O(4))(C(12)H(11)N(5))(2)(H(2)O)](n), the Cu(II) ion is five-coordinated by two carboxylate O atoms from two symmetry-related benzene-1,4-dicarboxylate ligands, two N atoms from two symmetry-related N (6)-benzyladenine ligands and one water O atom in a square-pyramidal environment. The Cu(II) and water O atoms lie on a twofold rotation axis, and the benzene-1,4-dicarboxylate ligand lies on an inversion center. The water O atom occupies the apical position and the basal plane is occupied by two O atoms and two N atoms. Each benzene-1,4-dicarboxylate anion acts as a bis-monodentate ligand that binds two Cu(II) cations, forming an infinite chain extending parallel to [001]. The N (6)-benzyladenine ligands are attached on both sides of the chain. Neighboring chains are further interconnected into the resulting three-dimensional supramolecular architecture via O—H⋯O, N—H⋯O and N—H⋯N hydrogen bonds. |
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