Tetra­aqua­{1-[(1H-1,2,3-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole}sulfato­cadmium dihydrate

In the title complex, [Cd(SO(4))(C(9)H(8)N(6))(H(2)O)(4)]·2H(2)O, the Cd(II) ion is six-coordinated by one N atom from a 1-[(1H-1,2,3-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole ligand and by five O atoms from four water mol­ecules and one monodentate sulfate anion in a distorted octa­hedral geomet...

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Detalles Bibliográficos
Autores principales: Li, Yu-xian, Li, Da-wei, Zhao, Dong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200735/
https://www.ncbi.nlm.nih.gov/pubmed/22058864
http://dx.doi.org/10.1107/S1600536811032442
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author Li, Yu-xian
Li, Da-wei
Zhao, Dong
author_facet Li, Yu-xian
Li, Da-wei
Zhao, Dong
author_sort Li, Yu-xian
collection PubMed
description In the title complex, [Cd(SO(4))(C(9)H(8)N(6))(H(2)O)(4)]·2H(2)O, the Cd(II) ion is six-coordinated by one N atom from a 1-[(1H-1,2,3-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole ligand and by five O atoms from four water mol­ecules and one monodentate sulfate anion in a distorted octa­hedral geometry. The sulfate tetra­hedron is rotationally disordered over two positions in a 0.651 (12):0.349 (12) ratio. In the crystal, adjacent mol­ecules are linked through O—H⋯O and O—H⋯N hydrogen bonds into a three-dimensional network.
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spelling pubmed-32007352011-11-06 Tetra­aqua­{1-[(1H-1,2,3-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole}sulfato­cadmium dihydrate Li, Yu-xian Li, Da-wei Zhao, Dong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cd(SO(4))(C(9)H(8)N(6))(H(2)O)(4)]·2H(2)O, the Cd(II) ion is six-coordinated by one N atom from a 1-[(1H-1,2,3-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole ligand and by five O atoms from four water mol­ecules and one monodentate sulfate anion in a distorted octa­hedral geometry. The sulfate tetra­hedron is rotationally disordered over two positions in a 0.651 (12):0.349 (12) ratio. In the crystal, adjacent mol­ecules are linked through O—H⋯O and O—H⋯N hydrogen bonds into a three-dimensional network. International Union of Crystallography 2011-08-17 /pmc/articles/PMC3200735/ /pubmed/22058864 http://dx.doi.org/10.1107/S1600536811032442 Text en © Li et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Yu-xian
Li, Da-wei
Zhao, Dong
Tetra­aqua­{1-[(1H-1,2,3-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole}sulfato­cadmium dihydrate
title Tetra­aqua­{1-[(1H-1,2,3-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole}sulfato­cadmium dihydrate
title_full Tetra­aqua­{1-[(1H-1,2,3-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole}sulfato­cadmium dihydrate
title_fullStr Tetra­aqua­{1-[(1H-1,2,3-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole}sulfato­cadmium dihydrate
title_full_unstemmed Tetra­aqua­{1-[(1H-1,2,3-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole}sulfato­cadmium dihydrate
title_short Tetra­aqua­{1-[(1H-1,2,3-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole}sulfato­cadmium dihydrate
title_sort tetra­aqua­{1-[(1h-1,2,3-benzotriazol-1-yl)meth­yl]-1h-1,2,4-triazole}sulfato­cadmium dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200735/
https://www.ncbi.nlm.nih.gov/pubmed/22058864
http://dx.doi.org/10.1107/S1600536811032442
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AT lidawei tetraaqua11h123benzotriazol1ylmethyl1h124triazolesulfatocadmiumdihydrate
AT zhaodong tetraaqua11h123benzotriazol1ylmethyl1h124triazolesulfatocadmiumdihydrate

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