Cargando…
Diacetato-κO;κ(2) O,O′-aqua(2,4,6-tri-2-pyridyl-1,3,5-triazine-κ(3) N (2),N (1),N (6))manganese(II) monohydrate
The Mn(II) ion in the title compound, [Mn(CH(3)CO(2))(2)(C(18)H(12)N(6))(H(2)O)]·H(2)O, is seven-coordinated in an approximately pentagonal–bipyramidal geometry by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and four O atoms from two distinct anionic acetato ligands an...
Autor principal: | |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200744/ https://www.ncbi.nlm.nih.gov/pubmed/22058860 http://dx.doi.org/10.1107/S1600536811032016 |
Sumario: | The Mn(II) ion in the title compound, [Mn(CH(3)CO(2))(2)(C(18)H(12)N(6))(H(2)O)]·H(2)O, is seven-coordinated in an approximately pentagonal–bipyramidal geometry by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and four O atoms from two distinct anionic acetato ligands and a water molecule. One acetate anion chelates the Mn atom via two O atoms occupying equatorial positions, and the other anion coordinates the Mn atom as a monodentate ligand via one O atom. The complex and solvent water molecules are linked by inter- and intramolecular O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds into a three-dimensional network. |
---|