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Diacetato-κO;κ(2) O,O′-aqua­(2,4,6-tri-2-pyridyl-1,3,5-triazine-κ(3) N (2),N (1),N (6))manganese(II) monohydrate

The Mn(II) ion in the title compound, [Mn(CH(3)CO(2))(2)(C(18)H(12)N(6))(H(2)O)]·H(2)O, is seven-coordinated in an approximately penta­gonal–bipyramidal geometry by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and four O atoms from two distinct anionic acetato ligands an...

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Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200744/
https://www.ncbi.nlm.nih.gov/pubmed/22058860
http://dx.doi.org/10.1107/S1600536811032016
Descripción
Sumario:The Mn(II) ion in the title compound, [Mn(CH(3)CO(2))(2)(C(18)H(12)N(6))(H(2)O)]·H(2)O, is seven-coordinated in an approximately penta­gonal–bipyramidal geometry by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and four O atoms from two distinct anionic acetato ligands and a water mol­ecule. One acetate anion chelates the Mn atom via two O atoms occupying equatorial positions, and the other anion coordinates the Mn atom as a monodentate ligand via one O atom. The complex and solvent water mol­ecules are linked by inter- and intra­molecular O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds into a three-dimensional network.